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New PFASs Identified in AFFF Impacted Groundwater by Passive Sampling and Nontarget Analysis.
Ghorbani Gorji, Sara; Gómez Ramos, María José; Dewapriya, Pradeep; Schulze, Bastian; Mackie, Rachel; Nguyen, Thi Minh Hong; Higgins, Christopher P; Bowles, Karl; Mueller, Jochen F; Thomas, Kevin V; Kaserzon, Sarit L.
Afiliación
  • Ghorbani Gorji S; Queensland Alliance for Environmental Health Sciences (QAEHS), The University of Queensland, 20 Cornwall Street, Woolloongabba 4102, QLD, Australia.
  • Gómez Ramos MJ; Chemistry and Physics Department, University of Almeria, Agrifood Campus of International Excellence (ceiA3), 04120 Almería, Spain.
  • Dewapriya P; Queensland Alliance for Environmental Health Sciences (QAEHS), The University of Queensland, 20 Cornwall Street, Woolloongabba 4102, QLD, Australia.
  • Schulze B; Queensland Alliance for Environmental Health Sciences (QAEHS), The University of Queensland, 20 Cornwall Street, Woolloongabba 4102, QLD, Australia.
  • Mackie R; Queensland Alliance for Environmental Health Sciences (QAEHS), The University of Queensland, 20 Cornwall Street, Woolloongabba 4102, QLD, Australia.
  • Nguyen TMH; Queensland Alliance for Environmental Health Sciences (QAEHS), The University of Queensland, 20 Cornwall Street, Woolloongabba 4102, QLD, Australia.
  • Higgins CP; Department of Civil and Environmental Engineering, Colorado School of Mines, Golden, Colorado 80401, United States.
  • Bowles K; Jacobs, North Sydney 2060, Australia.
  • Mueller JF; Queensland Alliance for Environmental Health Sciences (QAEHS), The University of Queensland, 20 Cornwall Street, Woolloongabba 4102, QLD, Australia.
  • Thomas KV; Queensland Alliance for Environmental Health Sciences (QAEHS), The University of Queensland, 20 Cornwall Street, Woolloongabba 4102, QLD, Australia.
  • Kaserzon SL; Queensland Alliance for Environmental Health Sciences (QAEHS), The University of Queensland, 20 Cornwall Street, Woolloongabba 4102, QLD, Australia.
Environ Sci Technol ; 58(3): 1690-1699, 2024 Jan 23.
Article en En | MEDLINE | ID: mdl-38189783
ABSTRACT
Monitoring contamination from per- and polyfluoroalkyl substances (PFASs) in water systems impacted by aqueous film-forming foams (AFFFs) typically addresses a few known PFAS groups. Given the diversity of PFASs present in AFFFs, current analytical approaches do not comprehensively address the range of PFASs present in these systems. A suspect-screening and nontarget analysis (NTA) approach was developed and applied to identify novel PFASs in groundwater samples contaminated from historic AFFF use. A total of 88 PFASs were identified in both passive samplers and grab samples, and these were dominated by sulfonate derivatives and sulfonamide-derived precursors. Several ultrashort-chain (USC) PFASs (≤C3) were detected, 11 reported for the first time in Australian groundwater. Several transformation products were identified, including perfluoroalkane sulfonamides (FASAs) and perfluoroalkane sulfinates (PFASis). Two new PFASs were reported (((perfluorohexyl)sulfonyl)sulfamic acid; m/z 477.9068 and (E)-1,1,2,2,3,3,4,5,6,7,8,8,8-tridecafluorooct-6-ene-1-sulfonic acid; m/z 424.9482). This study highlights that several PFASs are overlooked using standard target analysis, and therefore, the potential risk from all PFASs present is likely to be underestimated.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Contaminantes Químicos del Agua / Agua Subterránea / Fluorocarburos Tipo de estudio: Prognostic_studies País/Región como asunto: Oceania Idioma: En Revista: Environ Sci Technol Año: 2024 Tipo del documento: Article País de afiliación: Australia Pais de publicación: Estados Unidos
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Contaminantes Químicos del Agua / Agua Subterránea / Fluorocarburos Tipo de estudio: Prognostic_studies País/Región como asunto: Oceania Idioma: En Revista: Environ Sci Technol Año: 2024 Tipo del documento: Article País de afiliación: Australia Pais de publicación: Estados Unidos