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Porous phenolic resin regulated by alcohol-based deep eutectic solvent for selective extraction and separation of tanshinones from Salvia miltiorrhiza.
Tang, Weiyang; Wang, Meiting; Wu, Yelu; Row, Kyung Ho; Zhou, Jian-Liang.
Afiliación
  • Tang W; School of Pharmacy, Hangzhou Normal University, Hangzhou, Zhejiang, 311121, China. Electronic address: tangweiyang@hznu.edu.cn.
  • Wang M; School of Pharmacy, Hangzhou Normal University, Hangzhou, Zhejiang, 311121, China.
  • Wu Y; Innovation Research Institute of Traditional Chinese Medicine, Shanghai University of Traditional Chinese Medicine, Shanghai, 201203, China.
  • Row KH; Department of Chemistry and Chemical Engineering, Education and Research Center for Smart Energy and Materials, Inha University, Incheon, 402-701, South Korea.
  • Zhou JL; School of Pharmacy, Hangzhou Normal University, Hangzhou, Zhejiang, 311121, China. Electronic address: cpuzhou@hznu.edu.cn.
Talanta ; 270: 125558, 2024 Apr 01.
Article en En | MEDLINE | ID: mdl-38183713
ABSTRACT
Deep eutectic solvents (DES), regarded as promising green solvents, have gained attention due to their distinctive properties, particularly in analytical chemistry. While the use of DES in solvent extraction and separation has been extensively studied, its application in the synthesis of adsorbents has just begun. Phenolic resin, with its polyhydroxy structure and stable spherical morphology, could serve as an effective as adsorbents for enrichment of active ingredients in herbal medicine. Designing adsorbents with high selectivity and adsorption capacity presents a critical challenge in the enrichment of active ingredients in herbal medicine. In this study, alcohol-based DESs were employed as regulators of morphology and structure instead of organic solvents, facilitating the creation of polyhydroxy structure, adjustable pores and high specific surface areas. The resulting DES-regulated porous phenolic resin demonstrated enhanced extraction and separation capacity for active ingredients compared to conventional spherical phenolic resin owing to the alcohol-based DES offering more interaction modes with the analytes.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fenoles / Polímeros / Salvia miltiorrhiza / Abietanos / Formaldehído Idioma: En Revista: Talanta Año: 2024 Tipo del documento: Article Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fenoles / Polímeros / Salvia miltiorrhiza / Abietanos / Formaldehído Idioma: En Revista: Talanta Año: 2024 Tipo del documento: Article Pais de publicación: Países Bajos