An 'active site anchoring' strategy for the preparation of PBO fiber derived carbon catalyst towards an efficient oxygen reduction reaction and zinc-air batteries.
RSC Adv
; 13(51): 36424-36429, 2023 Dec 08.
Article
en En
| MEDLINE
| ID: mdl-38099260
ABSTRACT
In order to promote the wide application of clean energy-fuel cells, it is urgent to develop transition metal-based high-efficiency oxygen reduction reaction (ORR) catalytic materials with a low cost and available rich raw material resources to replace the currently used precious metal platinum-based catalytic materials. Herein, a novel 'active-site-anchoring' strategy was developed to synthesize highly-activated carbon-based ORR catalysts. Firstly, poly(p-phenylene benzobisoxazole) (PBO) fiber with a stable chemical structure was selected as the main precursor, and iron was complexed on its surface, and then poly-dopamine (PDA) was coated on the surface of PBO-Fe to form a PBO-Fe-PDA composite structure. Therefore, carbon-based catalyst PBO-Fe-PDA-900 with abundant Fe2O3 active sites was prepared by anchoring iron sites by PDA after pyrolysis. As a result, the PBO-Fe-PDA-900 catalyst displayed a 30 mV higher half-wave potential (0.86 V) than that of a commercial Pt/C electrocatalyst. Finally, PBO-Fe-PDA-900 was used as a cathode material for zinc-air batteries, showing a high peak power density superior to Pt/C. This work offers new prospects for the design of efficient, non-precious metal-based materials in zinc-air batteries.
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01-internacional
Base de datos:
MEDLINE
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En
Revista:
RSC Adv
Año:
2023
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Article
Pais de publicación:
Reino Unido