Enhancing Intrinsic Magnetic Hardness by Modulating Antagonistic Interactions in the Rare-Earth-Free Magnetic Solid Solution Hf2 Fe1-δ Ru5-x Irx+δ B2.
Chemistry
; 30(13): e202303381, 2024 Mar 01.
Article
en En
| MEDLINE
| ID: mdl-37996962
The quinary members in the solid solution Hf2 Fe1-δ Ru5-x Irx+δ B2 (x=1-4, VE=63-66) have been investigated experimentally and computationally. They were synthesized via arc-melting and analyzed by EDX and X-ray diffraction. Density functional theory (DFT) calculations predicted a preference for magnetic ordering in all members, but with a strong competition between ferro- and antiferromagnetism arising from interchain Fe-Fe interactions. The spin exchange and magnetic anisotropy energies predicted the lowest magnetic hardness for x=1 and 3 and the highest for x=2. Magnetization measurements confirm the DFT predictions and demonstrate that the antiferromagnetic ordering (TN =55-70â
K) found at low magnetic fields changed to ferromagnetic (TC =150-750â
K) at higher fields, suggesting metamagnetic behavior for all samples. As predicted, Hf2 FeRu3 Ir2 B2 has the highest intrinsic coercivity (Hc =74â
kA/m) reported to date for Ti3 Co5 B2 -type phases. Furthermore, all coercivities outperform that of ferromagnetic Hf2 FeIr5 B2 , indicating the importance of AFM interactions in enhancing magnetic anisotropy in these materials. Importantly, two members (x=1 and 4) maintain intrinsic coercivities in the semi-hard range at room temperature. This study opens an avenue for controlling magnetic hardness by modulating antagonistic AFM and FM interactions in low-dimensional rare-earth-free magnetic materials.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chemistry
Asunto de la revista:
QUIMICA
Año:
2024
Tipo del documento:
Article
País de afiliación:
Estados Unidos
Pais de publicación:
Alemania