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Visible-light induced C(sp3)-H arylation of glycine derivatives by cerium catalysis.
Wang, Shutao; Ye, Yanjie; Shen, Hailong; Liu, Jiyu; Liu, Zhao; Jiang, Zhigen; Lei, Junqiang; Zhang, Yuan.
Afiliación
  • Wang S; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.
  • Ye Y; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.
  • Shen H; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.
  • Liu J; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.
  • Liu Z; First Hospital of Lanzhou University, Lanzhou 730000, P. R. China.
  • Jiang Z; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.
  • Lei J; First Hospital of Lanzhou University, Lanzhou 730000, P. R. China.
  • Zhang Y; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou 730000, P. R. China. zhangyuan@lzu.edu.cn.
Org Biomol Chem ; 21(41): 8364-8371, 2023 Oct 25.
Article en En | MEDLINE | ID: mdl-37815482
A Ce(III)-catalyzed, visible-light induced aerobic oxidative dehydrogenative coupling reaction between glycine derivatives and electron-rich arenes is disclosed. The protocol proceeds efficiently under mild conditions, providing an efficient method for the rapid synthesis of α-arylglycine derivatives without the need for an external photosensitizer and additional oxidant. Moreover, this protocol could be performed on a 5 mmol scale, without obvious reduction of the efficiency.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2023 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2023 Tipo del documento: Article Pais de publicación: Reino Unido