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Late-stage Ligand Modification After Coordination Strengthens Stereoselectively Self-Assembled Hemiaminal Ether Complexes.
Raje, Sakthi; Koner, Abhishek; Ghosh, Suchismita; Butcher, Ray J; Mathivathanan, Logesh; Sundararajan, Mahesh; Angamuthu, Raja.
Afiliación
  • Raje S; Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India.
  • Koner A; Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India.
  • Ghosh S; Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India.
  • Butcher RJ; Department of Chemistry, Howard University, Washington, D.C., 20059, USA.
  • Mathivathanan L; Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology, Vellore, Tamil Nadu, 632014, India.
  • Sundararajan M; Theoretical Chemistry Section, Chemistry Division, Bhabha Atomic Research Centre, Mumbai-400085 (India), Homi Bhabha National Institute, Mumbai, 400085, India.
  • Angamuthu R; Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India.
Chem Asian J ; 18(20): e202300706, 2023 Oct 17.
Article en En | MEDLINE | ID: mdl-37655885
Fragile hemiaminal ether linkages present in the backbone of koneramines (LR OR'), tridentate ligands, bound to copper(II) in stereoselectively self-assembled syn-[Cu(LR OR')X2 ] complexes were transformed into sturdy methylene linkages to make corresponding rac-[Cu(LR H)Cl2 ] complexes by late-stage ligand modification after coordination with the retention of coordination sphere. The generality of stereoselective self-assembly of koneramine complexes is shown by utilising a number of metal ions, anions, amines, alcohols and thiols with complete characterisations.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Asian J Año: 2023 Tipo del documento: Article País de afiliación: India Pais de publicación: Alemania
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Asian J Año: 2023 Tipo del documento: Article País de afiliación: India Pais de publicación: Alemania