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The positive correlation between the dispersion and catalytic performance of Fe2O3 nanoparticles in nano-Fe2O3-ultrafine AP energetic composites supported by solid UV-vis spectroscopy.
Kou, Yong; Luo, Peng; Xiao, Lei; Xin, Yanping; Zhang, Guangpu; Hu, Yubing; Gao, Hongxu; Zhao, Fengqi; Jiang, Wei; Hao, Gazi.
Afiliación
  • Kou Y; National Special Superfine Powder Engineering Research Center of China, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. 15005161138@163.com.
  • Luo P; Xi'an North Huian Chemical Industry Co. Ltd, Xi'an, 710302, China.
  • Xiao L; National Special Superfine Powder Engineering Research Center of China, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. 15005161138@163.com.
  • Xin Y; Xi'an North Huian Chemical Industry Co. Ltd, Xi'an, 710302, China.
  • Zhang G; National Special Superfine Powder Engineering Research Center of China, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. 15005161138@163.com.
  • Hu Y; National Special Superfine Powder Engineering Research Center of China, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. 15005161138@163.com.
  • Gao H; Xi'an Modern Chemistry Research Institute, Xi'an 710065, China.
  • Zhao F; Xi'an Modern Chemistry Research Institute, Xi'an 710065, China.
  • Jiang W; National Special Superfine Powder Engineering Research Center of China, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. 15005161138@163.com.
  • Hao G; National Special Superfine Powder Engineering Research Center of China, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. 15005161138@163.com.
Dalton Trans ; 52(36): 12796-12807, 2023 Sep 19.
Article en En | MEDLINE | ID: mdl-37622218
Recently, the widespread use of nanocatalytic materials has contributed to an enormous improvement in the performance of energetic materials, especially, highly dispersed nanomaterials. However, the lack of quantitative methods for analyzing the dispersion of nanomaterials limits their further widespread use. Although various techniques such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), etc. are used to analyze the relative dispersion of nanomaterials, it is not possible to quantitatively analyze their dispersion. Therefore, there has been an effort to develop new methods for the quantitative analysis of nanocatalytic materials. Fortunately, we were able to analyze the dispersion of nanocatalytic materials using the difference in their UV absorbance. More importantly, we established the corresponding difference equation to quantify the dispersion of nanocatalytic materials, which is capable of quantifying the dispersion of nano-Fe2O3 in nano-Fe2O3-ultrafine AP composites. The accuracy of the difference equation was verified using a variety of techniques and the desired results were obtained. Based on the above conclusions, the quantitative analysis method for the dispersion of nanomaterials that we established is expected to be widely used and promote the development of energetic materials.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido