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Structural and Optical Characterizations of Polymethyl Methacrylate Films with the Incorporation of Ultrafine SiO2/TiO2 Composites Utilized as Self-Cleaning Surfaces.
Songpanit, Maneerat; Boonyarattanakalin, Kanokthip; Limwichean, Saksorn; Lertvanithphol, Tossaporn; Horprathum, Mati; Pecharapa, Wisanu; Mekprasart, Wanichaya.
Afiliación
  • Songpanit M; College of Materials Innovation and Technology, King Mongkut's Institute of Technology Ladkrabang, Bangkok 10520, Thailand.
  • Boonyarattanakalin K; College of Materials Innovation and Technology, King Mongkut's Institute of Technology Ladkrabang, Bangkok 10520, Thailand.
  • Limwichean S; National Electronics and Computer Technology Center (NECTEC), National Science and Technology Development Agency (NSTDA), Pathum Thani 12120, Thailand.
  • Lertvanithphol T; National Electronics and Computer Technology Center (NECTEC), National Science and Technology Development Agency (NSTDA), Pathum Thani 12120, Thailand.
  • Horprathum M; National Electronics and Computer Technology Center (NECTEC), National Science and Technology Development Agency (NSTDA), Pathum Thani 12120, Thailand.
  • Pecharapa W; College of Materials Innovation and Technology, King Mongkut's Institute of Technology Ladkrabang, Bangkok 10520, Thailand.
  • Mekprasart W; College of Materials Innovation and Technology, King Mongkut's Institute of Technology Ladkrabang, Bangkok 10520, Thailand.
Polymers (Basel) ; 15(15)2023 Jul 25.
Article en En | MEDLINE | ID: mdl-37571056
The structural and optical characterizations of nanocomposite films of polymethyl methacrylate (PMMA) and SiO2/TiO2 composites prepared via the spin-coating technique were investigated using different SiO2:TiO2 ratios. The SiO2/TiO2 nanocomposites were synthesized using the sonochemical process with Si:Ti precursor ratios of 1:0.1, 1:0.5, 1:1, 1:2, 1:4, and 0:1. All characterizations of ultrafine SiO2/TiO2 particles were loaded at 1 wt.% in a PMMA matrix for the fabrication of transparent SiO2/TiO2/PMMA composite films. The phase structure and morphology of SiO2/TiO2/PMMA composite films were monitored using X-ray diffraction, optical microscopy, and field-emission scanning electron microscopy. A surface roughness analysis of SiO2/TiO2/PMMA nanocomposite films was conducted using atomic force microscopy. For optical characterization, transmission properties with different incident angles of SiO2/TiO2/PMMA composite films were analyzed with UV-vis spectrophotometry. The water contact angles of SiO2/TiO2/PMMA composite films were analyzed to identify hydrophilic properties on film surfaces. Photocatalytic reactions in SiO2TiO2 composite films under UV irradiation were evaluated using rhodamine B dye degradation. The optimal condition of SiO2/TiO2/PMMA nanocomposite films was obtained at a 1:1 SiO2:TiO2 ratio in self-cleaning applications, resulting from good particle dispersion and the presence of the TiO2 phase in the composite.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2023 Tipo del documento: Article País de afiliación: Tailandia Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2023 Tipo del documento: Article País de afiliación: Tailandia Pais de publicación: Suiza