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Investigation of Structural, Dielectric and Optical Properties of Polyaniline-Magnesium Ferrite Composites.
Kolhar, Priyanka; Sannakki, Basavaraja; Verma, Meenakshi; Suresha, Siddaramappa; Alshehri, Mansoor; Shah, Nehad Ali.
Afiliación
  • Kolhar P; Department of Physics, Gulbarga University, Kalaburgi 585106, Karnataka, India.
  • Sannakki B; Department of Physics, Gulbarga University, Kalaburgi 585106, Karnataka, India.
  • Verma M; University Centre for Research and Development, Chandigarh University, Gharuan, Mohali 160055, Punjab, India.
  • Suresha S; Department of Physics, Government First Grade College, Holalkere 577552, Karnataka, India.
  • Alshehri M; Department of Mathematics, College of Sciences, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia.
  • Shah NA; Department of Mechanical Engineering, Sejong University, Seoul 05006, Republic of Korea.
Nanomaterials (Basel) ; 13(15)2023 Aug 02.
Article en En | MEDLINE | ID: mdl-37570551
A study on the influence of magnesium ferrite nanoparticles on the optical and dielectric attributes of Polyaniline has been conducted. Magnesium nano Ferrite powder is synthesized by the self-propagating solution combustion method. Polyaniline-Magnesium nano ferrite composites are synthesized by chemical oxidative polymerization of aniline with the addition of Magnesium nanoparticles. The samples are characterized with XRD and UV-Vis spectrometer, in the wavelength range of 200-800 nm and studied for optical properties. Dielectric properties are studied in the frequency range of 50 Hz to 5 MHz. X-ray diffraction reveals single phase formation of Magnesium ferrite, whereas Polyaniline shows an amorphous nature. In the XRD of the composites, we see the crystalline peaks of ferrite becoming more intense with the addition of ferrite and whereas the peak of Polyaniline diminishes. The crystallite size is quantified with the Debye-Scherrer formula, and it increases as the content of ferrite in the composites increases. The micro-strain decreases in the composites as the percentage of ferrite enhances in the composites. In the UV-Vis absorption spectra of composites, the peaks of Polyaniline shift to higher wavelength and there is also an absorption band in the spectra of composites corresponding to that of Magnesium ferrite particles. Both direct and indirect band gaps are calculated with the Tauc plot, and both the optical band gap decrease as the percentage of ferrite increases in the composite. The dielectric loss and dielectric constant both decrease with frequency in all the samples, and the dielectric response are in good agreement with Maxwell-Wagner model. Ferrite-polymer composites with both conducting and magnetic properties are considered useful for electromagnetic shielding and microwave absorption.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanomaterials (Basel) Año: 2023 Tipo del documento: Article País de afiliación: India Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanomaterials (Basel) Año: 2023 Tipo del documento: Article País de afiliación: India Pais de publicación: Suiza