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Nontarget and Comprehensive Analyses of Halogenated Organic Additives in Electrical Product Plastics by GC-NCI-Q-Orbitrap-HRMS and Cl/Br-Screening Algorithms.
Tang, Caiming; Zheng, Ruifen; Huang, Qiuxin; Xiong, Songsong; Zhu, Yizhe; Liang, Yutao; Zeng, Yan-Hong; Luo, Xiao-Jun; Mai, Bi-Xian.
Afiliación
  • Tang C; Laboratory of Advanced Analytical Chemistry and Detection Technology, Research Center for Eco-Environmental Engineering, Dongguan University of Technology, Dongguan 523808, China.
  • Zheng R; State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China.
  • Huang Q; Laboratory of Advanced Analytical Chemistry and Detection Technology, Research Center for Eco-Environmental Engineering, Dongguan University of Technology, Dongguan 523808, China.
  • Xiong S; CEPREI Environmental Assessment and Monitoring Center, The 5th Electronics Research Institute of the Ministry of Industry and Information Technology, Guangzhou 510610, China.
  • Zhu Y; CEPREI Environmental Assessment and Monitoring Center, The 5th Electronics Research Institute of the Ministry of Industry and Information Technology, Guangzhou 510610, China.
  • Liang Y; Laboratory of Advanced Analytical Chemistry and Detection Technology, Research Center for Eco-Environmental Engineering, Dongguan University of Technology, Dongguan 523808, China.
  • Zeng YH; Laboratory of Advanced Analytical Chemistry and Detection Technology, Research Center for Eco-Environmental Engineering, Dongguan University of Technology, Dongguan 523808, China.
  • Luo XJ; State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China.
  • Mai BX; State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China.
Anal Chem ; 95(26): 10052-10060, 2023 07 04.
Article en En | MEDLINE | ID: mdl-37337419
Halogenated organic additives (HOAs) are used in plastic components of various electrical products, potentially causing detrimental effects on the eco-environment and humans. Besides reported HOAs, many unknown HOAs may be present in electrical product plastics and urgently require identification and characterization. This study performed nontarget analysis and comprehensive characterization of HOAs in three typical electrical product plastics by nontarget analysis using gas chromatography-negative chemical ionization-high-resolution mass spectrometry in association with in-house-developed chlorine/bromine-specific data-processing algorithms. A total of 674 formulas of HOAs were identified in the plastics dismantled from three electrical products, among which 166, 362, and 146 were organochlorines, organobromines, and mix-chlorinated/brominated organic compounds, respectively. The identified HOAs were semiquantified, and the total concentrations of HOAs in individual plastics were 445-1549 ng/g. Organobromines showed the most species and the highest abundances in all of the plastics, of which the abundances accounted for 86.6-98.0% of the total HOAs. Partial HOAs (209 formulas) were tentatively structurally elucidated, which were classified into 13 groups, i.e., halogenated alkyl phenoxyethyls (H-alkyl phenoxyethyls), H-alkylbenzenes, H-benzenes, H-bisphenol A (H-BPAs), H-dioxins, H-diphenyl ethers, H-biphenyls/terphenyls, H-polycyclic aromatic hydrocarbons, H-phenols, H-phenyl esters, H-phenyl-aldehydes/ketones, H-quinones, and an undefined group containing the HOAs such as dechlorane plus and chlordane. H-BPAs were the predominant HOAs in the plastics, showing relatively high concentrations (13-281 ng/g), and tetrabromobisphenol A was the most abundant H-BPA, with the concentrations of 9-196 ng/g. The comprehensive characterization results represent a holistic picture on the species features and abundance distributions of HOAs in electrical product plastics and provide an inventory of crucial HOAs worthy of concern. HOAs may migrate from plastics and release into the environment and are possibly an important source of halogenated organic pollutants in the environment, thus calling for further investigation and proper regulation.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Dioxinas / Contaminantes Ambientales / Hidrocarburos Clorados Tipo de estudio: Diagnostic_studies / Screening_studies Límite: Humans Idioma: En Revista: Anal Chem Año: 2023 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Dioxinas / Contaminantes Ambientales / Hidrocarburos Clorados Tipo de estudio: Diagnostic_studies / Screening_studies Límite: Humans Idioma: En Revista: Anal Chem Año: 2023 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos