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The Significance of Hypervariability and Conserved Motifs in Antimicrobial Peptides from Tree Frogs.
Brunetti, Andrés E; Fuzo, Carlos A; Aguilar, Silvana; Rivera-Correa, Mauricio; Marani, Mariela M; Lopes, Norberto P.
Afiliación
  • Brunetti AE; Instituto de Biología Subtropical (IBS, UNaM-CONICET), Félix de Azara 1552, Posadas, CP 3300, Misiones, Argentina.
  • Fuzo CA; NPPNS, Department of Biomolecular Sciences, Faculty of Pharmaceutical Sciences of Ribeirão Preto, University of São Paulo, Ribeirão Preto, SP 14040-903, Brazil.
  • Aguilar S; Departamento de Análises Clínicas, Toxicológicas e Bromatológicas, Faculdade de Ciências Farmacêuticas de Ribeirão Preto, Universidade de São Paulo, 14040-903 Ribeirão Preto, SP, Brazil.
  • Rivera-Correa M; IPEEC-CONICET, Consejo Nacional de Investigaciones Científicas y Técnicas, Boulevard Brown 2915, U9120ACD Puerto Madryn, Argentina.
  • Marani MM; Laboratorio de Anfibios, Instituto de Ciencias Naturales, Universidad Nacional de Colombia, Bogota, 111321, Colombia.
  • Lopes NP; IPEEC-CONICET, Consejo Nacional de Investigaciones Científicas y Técnicas, Boulevard Brown 2915, U9120ACD Puerto Madryn, Argentina.
J Nat Prod ; 86(7): 1761-1769, 2023 07 28.
Article en En | MEDLINE | ID: mdl-37219414
Amphibians' skin is a rich source of natural antimicrobial peptides (AMPs). These AMPs exhibit marked inter- and intraspecific sequence divergence linked to the arms race between host and pathogens. Here, we combine peptidomics, molecular modeling, and phylogenetic analyses to understand the evolution of AMPs in Cophomantini, a diverse clade of neotropical tree frogs, and to investigate their interaction with bacterial membranes. Consistent with results in other amphibians, all species of Cophomantini secrete a mixture of peptides. We selected the hylin peptide family to survey sequence variability and the presence of common amino acid motifs. We found that most species secrete a unique set of hylins that, though variable, share the conserved motif Gly-X-X-X-Pro-Ala-X-X-Gly, with Gly and Pro colocalizing with charged or polar residues. Our modeling revealed that Pro curves the peptide through a hinge, facilitating its insertion into the bacterial membrane and, once inserted, contributes to stabilizing the pore structure. The phylogenetic inference using hylid prepro-peptides showed the need to classify new AMPs using the full-length sequence of the prepro-peptide region and highlighted the complex relationships between peptide families. Our findings revealed that conserved motifs occurred independently in distinct AMP families, suggesting a convergent evolution and a significant role in peptide-membrane interactions.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Péptidos / Péptidos Antimicrobianos Tipo de estudio: Prognostic_studies Límite: Animals / Humans Idioma: En Revista: J Nat Prod Año: 2023 Tipo del documento: Article País de afiliación: Argentina Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Péptidos / Péptidos Antimicrobianos Tipo de estudio: Prognostic_studies Límite: Animals / Humans Idioma: En Revista: J Nat Prod Año: 2023 Tipo del documento: Article País de afiliación: Argentina Pais de publicación: Estados Unidos