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Pillar[5]arene-Derived Terpyridinepalladium(II) Complex: Synthesis, Characterization, and Application in Green Catalysis.
Wang, Yang; Tang, Ruowen; Zhang, Yue; Dai, Yu; Zhou, Qixiang; Zhou, Youjun; Yan, Chao-Guo; Lu, Bing; Wang, Jin; Yao, Yong.
Afiliación
  • Wang Y; School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, P. R. China.
  • Tang R; School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, P. R. China.
  • Zhang Y; School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, P. R. China.
  • Dai Y; School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, P. R. China.
  • Zhou Q; School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, P. R. China.
  • Zhou Y; School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, P. R. China.
  • Yan CG; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225001, P. R. China.
  • Lu B; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225001, P. R. China.
  • Wang J; School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, P. R. China.
  • Yao Y; School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, P. R. China.
Inorg Chem ; 62(20): 7605-7610, 2023 May 22.
Article en En | MEDLINE | ID: mdl-37162421
Metal nanoparticle catalysts have attracted great interest because they possess high surface-to-volume ratios and exhibit a very large number of catalytically active sites per unit area. However, high surface-to-volume ratios will induce nanoparticle aggregates during the catalytic reactions, making them lose their catalytic activity. In this work, a monoterpyridine-unit-functionalized pillar[5]arene (TP5) was synthesized successfully, which can be used as anchoring sites for the controllable preparation of well-dispersed palladium nanoparticles [TP5/Pd(0) NPs]. The as-prepared TP5/Pd(0) NPs were fully characterized by X-ray photoelectron spectroscopy, transmission electron microscopy, and powder X-ray diffraction. Importantly, the ultrafine TP5/Pd(0) NPs are found to be excellent and reusable catalysts for the reduction of nitrophenols in aqueous solution.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2023 Tipo del documento: Article Pais de publicación: Estados Unidos
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2023 Tipo del documento: Article Pais de publicación: Estados Unidos