Structural Regulation and Oxygen Reduction Reaction Activity of [Co(bpy)2BO2(OH)] and [Cu(bpy)(OH)]2- Complex Templated Borates.

Liu, Lei; Qin, Jian-Peng; Liao, Zhen-Ping; Pan, Chun-Yang

Structural Regulation and Oxygen Reduction Reaction Activity of [Co(bpy)₂BO₂(OH)] and [Cu(bpy)(OH)]^2- Complex Templated Borates.

Liu, Lei; Qin, Jian-Peng; Liao, Zhen-Ping; Pan, Chun-Yang.

Afiliación

Liu L; School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China.
Qin JP; School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China.
Liao ZP; School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China.
Pan CY; School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China.

Inorg Chem ; 62(18): 6948-6954, 2023 May 08.

Article en En | MEDLINE | ID: mdl-37083401

RESUMEN

Two templated borates, [Co(bpy)2BO2(OH)]·[B5O6(OH)4]·H3BO3·H3O·H2O (1) and [Cu(bpy)(OH)]2·[B5O6(OH)4]2·H2O (2), have been synthesized successfully and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, and Fourier transform infrared. The [Co(bpy)2BO2(OH)] complex in 1 shows a very rare coordination mode between Co2+ and BO2(OH)2-. The structures of 1 and 2 can be adjusted by changing the reagent. The oxygen reduction reaction activity of these Co- and Cu-based catalysts was studied. The E1/2 values of Co-C-750 and Cu-C-750 are 0.864 and 0.837 V, respectively.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2023 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos

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