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Green Inhibition of Corrosion of Aluminium Alloy 5083 by Artemisia annua L. Extract in Artificial Seawater.
Zlatic, Gloria; Martinovic, Ivana; Pilic, Zora; Paut, Andrea; Mitar, Ivana; Prkic, Ante; Culum, Dusan.
Afiliación
  • Zlatic G; Department of Chemistry, Faculty of Science and Education, University of Mostar, 88 000 Mostar, Bosnia and Herzegovina.
  • Martinovic I; Department of Chemistry, Faculty of Science and Education, University of Mostar, 88 000 Mostar, Bosnia and Herzegovina.
  • Pilic Z; Department of Chemistry, Faculty of Science and Education, University of Mostar, 88 000 Mostar, Bosnia and Herzegovina.
  • Paut A; Faculty of Chemistry and Technology, University of Split, Ruder Boskovic 35, 21000 Split, Croatia.
  • Mitar I; Faculty of Science, University of Split, Ruder Boskovic 33, 21000 Split, Croatia.
  • Prkic A; Faculty of Chemistry and Technology, University of Split, Ruder Boskovic 35, 21000 Split, Croatia.
  • Culum D; Department of Chemistry, Faculty of Science, University of Sarajevo, 71 000 Sarajevo, Bosnia and Herzegovina.
Molecules ; 28(7)2023 Mar 23.
Article en En | MEDLINE | ID: mdl-37049660
Plant extracts are increasingly being examined in the corrosion inhibition of metal and alloys in various environments due to their potent antioxidant properties. The use of Artemisia annua L. aqueous extract (AAE) as an aluminium alloy 5083 (ALA) corrosion inhibitor in artificial seawater (ASW) was investigated using electrochemical tests and spectroscopy tools, while the active biocompounds found in AAE were analyzed using high-performance liquid chromatography (HPLC). Electrochemical results showed that AAE acts as an anodic inhibitor through the physisorption (ΔG ≈ -16.33 kJ mol-1) of extract molecules on the ALA surface, thus reducing the active sites for the dissolution of the alloy in ASW. Fourier-transform infrared spectra confirmed that phenolic acids found in AAE formed the surface layer that protects ALA against the corrosive marine environment, while HPLC analysis confirmed that the main phytoconstituents of AAE were chlorogenic acid and caffeic acid. The inhibition action of phenolic acids and their derivatives found in the AAE was based on the physisorption of caffeic acid on the ALA surface, which improved physicochemical properties of the barrier film and/or conversion of Al3+ to elemental aluminium by phenolic acids as reducens, which slowed down the diffusion rate of Al3+ to or from the ALA surfaces. The protective effect of the surface layer formed in the presence of AAE against ASW was also confirmed by inductively coupled plasma-optical emission spectrometry (ICP-OES) whereby the measured concentration of Al ions after 1 h of immersion of ALA in the pure ASW was 15.30 µg L-1 cm-2, while after the addition of 1 g L-1 AAE, the concentration was 3.09 µg L-1 cm-2.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Artemisia annua / Aleaciones Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2023 Tipo del documento: Article Pais de publicación: Suiza
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Artemisia annua / Aleaciones Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2023 Tipo del documento: Article Pais de publicación: Suiza