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In Situ Formed Heterostructure Interface and Well-Tuned Electronic Structure Ensuring Long Cycle Stability for 4.9 V High-Voltage Li-Rich Layered Oxide Cathodes.
Zhou, Gang; Zhang, Datong; Zhang, Youquan; Wang, Wenran; Uchiyama, Tomoki; Zhang, Chunxiao; Uchimoto, Yoshiharu; Wei, Weifeng.
Afiliación
  • Zhou G; School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan, Guangdong 523000, P. R. China.
  • Zhang D; State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083, P. R. China.
  • Zhang Y; Graduate School of Human and Environmental Studies, Kyoto University, Yoshida Nihonmatsu Cho, Sakyo, Kyoto 606-8501, Japan.
  • Wang W; State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083, P. R. China.
  • Uchiyama T; State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083, P. R. China.
  • Zhang C; Graduate School of Human and Environmental Studies, Kyoto University, Yoshida Nihonmatsu Cho, Sakyo, Kyoto 606-8501, Japan.
  • Uchimoto Y; State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083, P. R. China.
  • Wei W; Graduate School of Human and Environmental Studies, Kyoto University, Yoshida Nihonmatsu Cho, Sakyo, Kyoto 606-8501, Japan.
ACS Appl Mater Interfaces ; 15(15): 19055-19065, 2023 Apr 19.
Article en En | MEDLINE | ID: mdl-37036492
High-voltage lithium-rich manganese-based layered oxides (LMLOs) are considered as the most competitive cathode materials for next-generation high-energy-density lithium-ion batteries (LIBs). However, LMLOs still suffer from irreversible lattice oxygen release, uncontrollable interface side reactions, and surface structural degradation. Herein, we propose an integration strategy combining La/Al codoping and LixCoPO4 nanocoating to improve the electrochemical performance of LMLOs comprehensively. La/Al codoping regulates the electronic structure to enhance the redox activity of anions and cations and inhibit structural degradation. The LixCoPO4 nanocoating formed by in situ reaction with the surface residual lithium can not only promote Li-ion migration but also reduce interfacial side reactions. The induced Layered@Rocksalt@LixCoPO4 heterostructure suppresses lattice volume variation and structural degradation during cycling. Under the synergistic effect of the heterostructure interface and well-tuned electronic structure, the capacity retention rate of comodified LMLO materials reaches 80.06% after 500 cycles (2.0-4.65 V) and 75.1% after 340 cycles at 1C under a high cut-off voltage of 4.9 V.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2023 Tipo del documento: Article Pais de publicación: Estados Unidos
Texto completo
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XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2023 Tipo del documento: Article Pais de publicación: Estados Unidos