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The Preparation Process and Hydration Mechanism of Steel Slag-Based Ultra-Fine Tailing Cementitious Filler.
Zhang, Siqi; Wu, Bo; Ren, Yutong; Wu, Zeping; Li, Qian; Li, Keqing; Zhang, Minggen; Yu, Junhao; Liu, Jialu; Ni, Wen.
Afiliación
  • Zhang S; School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China.
  • Wu B; School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China.
  • Ren Y; School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China.
  • Wu Z; School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China.
  • Li Q; School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China.
  • Li K; School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China.
  • Zhang M; School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China.
  • Yu J; School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China.
  • Liu J; School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China.
  • Ni W; School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China.
Gels ; 9(2)2023 Jan 18.
Article en En | MEDLINE | ID: mdl-36826252
Steel slag, desulphurised ash, desulphurised gypsum and ultra-fine iron tailing sand are common industrial solid wastes with low utilisation rates. Herein, industrial solid wastes (steel slag, desulphurised gypsum and desulphurised ash) were used as the main raw materials to prepare a gelling material and ultra-fine tailing was used as an aggregate to prepare a new type of cementing filler for mine filling. The optimal composition of the cementing filler was 75% steel slag, 16.5% desulphurised gypsum, 8.75% desulphurised ash, 1:4 binders and tailing mass ration and 70% concentration. The compressive strength of the 28-day sample reached 1.24 MPa, meeting the mine-filling requirements, while that of the 90-day sample was 3.16 MPa. The microscopic analysis results showed that a small amount of C3A reacted with the sulphate in the desulphurised gypsum to form ettringite at the early stage of hydration after the steel slag was activated by the desulphurisation by-products. In addition, C2S produced hydrated calcium silicate gel in an alkaline environment. As hydration proceeded, the sulphite in the desulphurised ash was converted to provide sulphate for the later sustained reaction. Under the long-term joint action of alkali and sulphate, the reactive silica-oxygen tetrahedra and alumina-oxygen tetrahedra depolymerised and then polymerised, further promoting the hydration reaction to generate hydrated calcium silicate gel and ettringite. The low-carbon and low-cost filler studied in this paper represents a new methodology for the synergistic utilisation of multiple forms of solid waste.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Gels Año: 2023 Tipo del documento: Article País de afiliación: China Pais de publicación: Suiza
Texto completo
Añadir a Mi BVS
Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Gels Año: 2023 Tipo del documento: Article País de afiliación: China Pais de publicación: Suiza