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In Situ Hydrothermal Synthesis of Ni1-xMnxWO4 Nanoheterostructure for Enhanced Photodegradation of Methyl Orange.
Hasan, Imran; Albaeejan, Mohammed Abdullah; Alshayiqi, Alanoud Abdullah; Al-Nafaei, Wedyan Saud; Alharthi, Fahad A.
Afiliación
  • Hasan I; Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia.
  • Albaeejan MA; Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia.
  • Alshayiqi AA; Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia.
  • Al-Nafaei WS; Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia.
  • Alharthi FA; Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia.
Molecules ; 28(3)2023 Jan 23.
Article en En | MEDLINE | ID: mdl-36770807
The monoclinic nanocrystalline Ni1-xMnxWO4 heterostructure has been successfully synthesized by the hydrothermal technique for achieving better sensitive and photocatalytic performances. Different characterization techniques such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), ultraviolet-visible (UV-Vis), and photoluminescence (PL) spectroscopy have been employed to investigate their structural, microstructural, and optical properties. Mn-ion incorporation in the NiWO4 lattice reduces the particle size of the sample compared with the pure undoped NiWO4 sample, which has been confirmed from the transmission electron microscope image. The Tauc plot of the Ni1-xMnxWO4 sample exhibits a significant decrease in bandgap energy compared with the pure undoped NiWO4 sample due to the quantum confinement effect. Finally, the material was explored as a photocatalyst for the degradation of methyl orange (MO) dye from wastewater under visible light irradiation. Various reaction parameters such as pH, catalyst dose, reaction time, and kinetics of the photodegradation were studied using the batch method. The results showed that the Ni1-xMnxWO4 is highly efficient (94.51%) compared with undoped NiWO4 (65.45%). The rate of photodegradation by Ni1-xMnxWO4 (0.067) was found to be 1.06 times higher than the undoped NiWO4 (0.062).
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2023 Tipo del documento: Article País de afiliación: Arabia Saudita Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2023 Tipo del documento: Article País de afiliación: Arabia Saudita Pais de publicación: Suiza