Novel Insights on the Metal-Support Interactions of Pd/ZrO2 Catalysts on CH4 Oxidation.
ACS Appl Mater Interfaces
; 15(6): 7959-7968, 2023 Feb 15.
Article
en En
| MEDLINE
| ID: mdl-36744966
With the environmental harm of unburnt CH4 in natural gas vehicle exhaust, oxidizing CH4 to CO2 over catalysts at low temperatures becomes an exigent issue. Supported Pd catalysts possess higher CH4 activity than other noble metal catalysts. A series of Pd/ZrO2 catalysts were synthesized to research the potential relationship among Pd particle morphology, electron transfer, CH4 oxidation mechanism, and catalytic activity. Characterizations show that the ratio of PdOx facets to edge/corner sites on four catalysts increases in the order of PZ85 ≈ PZ40 < PZ55 < PZ70 because of the difference in content of surface -OH groups, and this order turns out to be the same as that of electron transfer intensity, revealing the degree of metal-support interactions. This kind of metal-support interaction in PZ70 can be helpful to accelerate CH4 combustion via promoting the break of the C-H bond and dissociation of CO3* according to density functional theory studies. T90 of the PZ70 catalyst with optimum catalytic activity reaches 331 °C.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
ACS Appl Mater Interfaces
Asunto de la revista:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Año:
2023
Tipo del documento:
Article
Pais de publicación:
Estados Unidos