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Chemoselective Oxidation of Alcohols in the Presence of Amines Using an Oxoammonium Salt.
Lewis, Stephonda G; Dadum, Abra G; McLean, David; Buenavista, Jhennalin; Myers, Jaileen; Lambert, Kyle M; Fair, Justin D.
Afiliación
  • Lewis SG; Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, Virginia, 23529, United States.
  • Dadum AG; Maida Department of Chemistry, Biochemistry, Physics and Engineering, Indiana University of Pennsylvania, Indiana, Pennsylvania 15705, United States.
  • McLean D; Maida Department of Chemistry, Biochemistry, Physics and Engineering, Indiana University of Pennsylvania, Indiana, Pennsylvania 15705, United States.
  • Buenavista J; Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, Virginia, 23529, United States.
  • Myers J; Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, Virginia, 23529, United States.
  • Lambert KM; Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, Virginia, 23529, United States.
  • Fair JD; Maida Department of Chemistry, Biochemistry, Physics and Engineering, Indiana University of Pennsylvania, Indiana, Pennsylvania 15705, United States.
Tetrahedron ; 1312023 Jan 26.
Article en En | MEDLINE | ID: mdl-36742269
The oxidation of alcohols in the presence of reactive amines employing the commercially available oxoammonium cation, "Bobbitt's salt" is described. The oxidation is accomplished under acidic conditions and subsequent treatment with a suitable base affords a convenient one-pot method to access imines in good to excellent isolated yields (74-99%).
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Tetrahedron Año: 2023 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Tetrahedron Año: 2023 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido