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Infrequent Cubane-Like Chromium Sulfide Cluster with σ-Donor Ligands with Efficient Electrocatalytic Property Toward Hydrogen Evolution Reaction.
Pei, Hong-Mei; Liu, Xing; Huang, Chun-Mei; Zhou, Jian; Zou, Hua-Hong.
Afiliación
  • Pei HM; Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 401331, P. R. China.
  • Liu X; Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 401331, P. R. China.
  • Huang CM; Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 401331, P. R. China.
  • Zhou J; Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 401331, P. R. China.
  • Zou HH; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy, Guangxi Normal University, Guilin 541004, P. R. China.
Inorg Chem ; 62(6): 2951-2957, 2023 Feb 13.
Article en En | MEDLINE | ID: mdl-36719137
The exploitation of efficient and economical electrocatalysts for hydrogen evolution reaction (HER) is of exceeding interest in renewable clean-energy technologies. Herein, the facile solvothermal reaction of S and chromic acetate in ethylenediamine (en) achieved a novel organic hybrid chromium sulfide [Cr4(µ3-S)4(en)4(SH)4]·0.25H2O (1), which offers a new type of antiferromagnetic cubane-like chromium sulfide cluster with σ-donor en ligands. 1 was utilized in combination with Ni nanoparticles and porous Ni foam (NF) to fabricate a Ni/1/NF electrode as an efficient cathodic catalyst, indicating excellent electrocatalytic property toward HER.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE País/Región como asunto: Cuba Idioma: En Revista: Inorg Chem Año: 2023 Tipo del documento: Article Pais de publicación: Estados Unidos
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE País/Región como asunto: Cuba Idioma: En Revista: Inorg Chem Año: 2023 Tipo del documento: Article Pais de publicación: Estados Unidos