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Iron(III) Arylhydrazone Complexes Immobilized on Amine-Functionalized Mesoporous Silica: Catalysts for the Valorization of Biomass-Derived Furfuryl Alcohol.
Soliman, Mohamed M A; Granadeiro, Carlos M; Balula, Salete S; Pombeiro, Armando J L; Mahmudov, Kamran T; Alegria, Elisabete C B A.
Afiliación
  • Soliman MMA; Centro de Química Estrutural, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001, Lisboa, Portugal.
  • Granadeiro CM; Departamento de Engenharia Química, Instituto Superior de Engenharia de Lisboa, Instituto Politécnico de Lisboa, R. Conselheiro Emídio Navarro, 1959-007, Lisboa, Portugal.
  • Balula SS; LAQV-REQUIMTE, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre s/n, 4169-007, Porto, Portugal.
  • Pombeiro AJL; LAQV-REQUIMTE, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre s/n, 4169-007, Porto, Portugal.
  • Mahmudov KT; Centro de Química Estrutural, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001, Lisboa, Portugal.
  • Alegria ECBA; Рeoples' Friendship University of Russia, RUDN University), Research Institute of Chemistry, 6 Miklukho-Maklaya Street, 117198, Moscow, Russian Federation.
Chempluschem ; 88(3): e202200363, 2023 Mar.
Article en En | MEDLINE | ID: mdl-36670086
The aquasoluble FeIII complexes [Fe(H2 O)3 (L1 )] ⋅ 4H2 O (Fe1) and [Fe(H2 O)3 (L2 )] ⋅ 3H2 O (Fe2), bearing the basic forms of 5-chloro-3-(2-(4,4-dimethyl-2,6-dioxocyclohexylidene)hydrazinyl)-2-hydroxy-benzenesulfonic acid (H3 L1 ) and 3-(2-(2,4-dioxopentan-3-ylidene)hydrazinyl)-2-hydroxy-5-nitrobenzenesulfonic acid (H3 L2 ), were incorporated for the first time into amine-functionalized SBA-15 support via an impregnation method. The successful preparation of the composites was confirmed by Fourier-Transform Infrared spectroscopy (FT-IR), powder X-ray diffraction (XRD), scanning electron microscope (SEM/EDS), transmission electron microscopy (TEM), elemental analysis, and nitrogen adsorption-desorption isotherms. The resulting Fe1@aptesSBA-15 and Fe2@aptesSBA-15 composites were tested as the first SBA-15-based heterogeneous catalysts for the conversion of furfuryl alcohol under mild reaction conditions (80 to 100 °C) and with an environmentally friendly oxidant (TBHP, 70 % aq. sol. with 1 : 1 oxidant/substrate molar ratio). The influence of various factors, such as reaction time, amounts of oxidant and catalyst, was investigated. The reaction time can be fairly reduced by adopting a microwave-assisted method allowing it to reach complete conversion after 0.25 h, in the absence of any added solvent or additive. Under these conditions, a vigorous furfuryl alcohol polymerization process occurred, with furfural as a by-product. Recycling studies were carried out for Fe2@aptesSBA-15 and after four consecutive runs, the overall conversion of furfuryl alcohol remained high (≥99 %), without an appreciable change in the obtained yield.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chempluschem Año: 2023 Tipo del documento: Article País de afiliación: Portugal Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chempluschem Año: 2023 Tipo del documento: Article País de afiliación: Portugal Pais de publicación: Alemania