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A facile precursor route towards the synthesis of Fe1-xS@NC-rGO composite anode materials for high-performance lithium-ion batteries.
Zhan, Guanghao; Yan, Ruibo; Liao, Wenhua; Hu, Qianqian; Huang, Xiaoying.
Afiliación
  • Zhan G; College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, PR. China.
  • Yan R; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, PR China. xyhuang@fjirsm.ac.cn.
  • Liao W; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, PR China. xyhuang@fjirsm.ac.cn.
  • Hu Q; College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian 350007, PR China.
  • Huang X; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, PR China. xyhuang@fjirsm.ac.cn.
Dalton Trans ; 52(6): 1711-1719, 2023 Feb 07.
Article en En | MEDLINE | ID: mdl-36651816
Iron-based sulfides are considered promising anode materials for lithium-ion batteries (LIBs) due to their low cost and high theoretical specific capacities. However, low conductivity and dissolution of lithium polysulfides during the reaction hamper their practical applications. Herein, we firstly synthesized N-doped carbon-coated Fe1-xS (Fe1-xS@NC) sheets through vacuum pyrolysis of the precursor Fe1-xS(en)0.5 (en = ethylenediamine). Then Fe1-xS@NC-rGO composites (rGO = reduced graphene oxide) were prepared in which the Fe1-xS@NC sheets were anchored on the rGO. The performance of the composites as an anode material for LIBs has been investigated. It is found that coating N-doped C on Fe1-xS surfaces can improve the surface conductivity and electrochemical kinetics of Fe1-xS, which is beneficial for the conversion between lithium polysulfides and Fe1-xS. In addition, the coated N-doped C on the Fe1-xS sheets can serve as a barrier to direct contact between the electrolyte and the material, reducing the dissolution of polysulfides and preventing the loss of active ingredients. More importantly, the double protection of the N-doped C layer and the flexible rGO substrate minimizes the structural damage caused by the cyclic expansion of Fe1-xS@NC-rGO. As expected, Fe1-xS@NC-rGO exhibits good rate performance with a reversible capacity of 939.5 mA h g-1 after 1690 cycles at a current density of 1.0 A g-1, along with outstanding charge and discharge performance and excellent long-term cycling stability. This work shows that the introduction of NC coating and the rGO matrix into Fe1-xS would synergistically enhance the performance of Fe1-xS for LIBs and highlights the effectiveness of the synthetic strategy for double carbon-based materials-protected sulfides in developing superior LIB electrodes.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article Pais de publicación: Reino Unido