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Controlling the Photofunctionality of a Polyanionic Heteroleptic Copper(I) Photosensitizer for CO2 Reduction Using Its Ion-pair Formation with Polycationic Ammonium in Aqueous Media.
Sueyoshi, Fumika; Zhang, Xian; Yamauchi, Kosei; Sakai, Ken.
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  • Sueyoshi F; Department of Chemistry, Faculty of Science, Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395, Japan.
  • Zhang X; Department of Chemistry, Faculty of Science, Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395, Japan.
  • Yamauchi K; Current address: Institute of Inorganic Chemistry, University of Göttingen, 37077, Göttingen, Germany.
  • Sakai K; Department of Chemistry, Faculty of Science, Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395, Japan.
Angew Chem Int Ed Engl ; 62(9): e202217807, 2023 Feb 20.
Article en En | MEDLINE | ID: mdl-36624554
A water-soluble trianionic heteroleptic copper(I) photosensitizer having four sulfonate groups (CuPS3- ) was found to afford the 1 : 2 ion-pair adduct with dicationic alkylammonium (hexamethonium) cations (HM2+ ) in aqueous media, leading to exhibit excellent photophysical and photocatalytic performances owing to the substantial suppression of water-derived non-radiative decay of the photoexcited state.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2023 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2023 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Alemania