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Development of Online pH Monitoring for Lactic, Malonic, Citric, and Oxalic Acids Based on Raman Spectroscopy Using Hierarchical Chemometric Modeling.
Heller, Forrest D; Ahlers, Laura R H; Nordquist, Zoe E; Gunawardena, Navindra H; French, Amanda D; Lines, Amanda M; Nelson, Gilbert L; Casella, Amanda J; Bryan, Samuel A.
Afiliación
  • Heller FD; Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
  • Ahlers LRH; Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
  • Nordquist ZE; Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
  • Gunawardena NH; Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
  • French AD; Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
  • Lines AM; Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
  • Nelson GL; Chemistry Department, The College of Idaho, Caldwell, Idaho 83605, United States.
  • Casella AJ; Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
  • Bryan SA; Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
Anal Chem ; 94(50): 17467-17476, 2022 12 20.
Article en En | MEDLINE | ID: mdl-36480638
Online spectroscopic measurements can be used to provide unique insight into complex chemical systems, enabling new understanding and optimization of chemical processes. A key example of this is discussed here with the monitoring of pH of various acid systems in real-time. In this work the acids used in multiple chemical separations processes, such as TALSPEAK (Trivalent Actinide-Lanthanide Separation by Phosphorus reagent Extraction from Aqueous Komplexes) and oxalate precipitation, were characterized. Raman spectroscopy, a robust optical approach that can be integrated in corrosive processes, was used to follow the unique fingerprints of the various protonated and deprotonated acid species. This data was analyzed using a hierarchical modeling approach to build a consolidated model scheme using optical fingerprints from all weak acids to measure pH associated with any of the weak acid systems studied here. Validation of system performance included utilizing Raman spectroscopy under dynamic flow conditions to monitor solution pH under changing process conditions in-line. Overall, the Raman based approach provided accurate analysis of weak acid solution pH.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Oxalatos / Espectrometría Raman Idioma: En Revista: Anal Chem Año: 2022 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Oxalatos / Espectrometría Raman Idioma: En Revista: Anal Chem Año: 2022 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos