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Anti-SARS-CoV-2 and cytotoxic activity of two marine alkaloids from green alga Caulerpa cylindracea Sonder in the Dardanelles.
Erol, Ebru; Orhan, Muge Didem; Avsar, Timucin; Akdemir, Atilla; Okudan, Emine Sukran; Alim Toraman, Gulbahar Ozge; Topcu, Gulacti.
Afiliación
  • Erol E; Dept. of Analytical Chemistry, Faculty of Pharmacy, Bezmialem Vakif University Istanbul Turkey.
  • Orhan MD; Bahcesehir University, Health Sciences Institute, Neuroscience Laboratory Istanbul Turkey.
  • Avsar T; Bahcesehir University, Health Sciences Institute, Neuroscience Laboratory Istanbul Turkey.
  • Akdemir A; Bahcesehir University, School of Medicine, Department of Medical Biology Istanbul Turkey.
  • Okudan ES; Computer-Aided Drug Discovery Lab., Dept. of Pharmacology, Faculty of Pharmacy, Bezmialem Vakif University Istanbul Turkey.
  • Alim Toraman GO; Faculty of Aquatic Sciences and Fisheries, Akdeniz University Antalya Turkey.
  • Topcu G; Dept. of Pharmacognosy, Faculty of Pharmacy, Bezmialem Vakif University Istanbul Turkey.
RSC Adv ; 12(46): 29983-29990, 2022 Oct 17.
Article en En | MEDLINE | ID: mdl-36321101
Caulerpa cylindracea Sonder is a green alga belonging to the Caulerpaceae family. This is the first chemical investigation of C. cylindracea in the Dardanelles which resulted in the isolation of four compounds, caulerpin (1), monomethyl caulerpinate (2), beta-sitosterol (3), and palmitic acid (4). Their structures were elucidated by spectroscopic analyses including 1D- and 2D NMR and mass. The isolated compounds 1 and 2 were tested against the SARS-CoV-2 viral targets spike protein and main protease (3CL) enzyme, and both compounds significantly inhibit the interaction of spike protein and ACE2, while the main protease activity was not significantly reduced. Docking studies suggested that compounds 1 and 2 may bind to the ACE2 binding pocket on spike, and compound 2 may also bind to an allosteric site on spike. As such, these compounds may inhibit the spike-ACE2 complex formation competitively and/or allosterically and have the potential to be used against SARS-CoV-2 virus infection. In addition, compounds 1 and 2 showed at least two-fold higher cytotoxicity against breast cancer cell lines MCF7 and MDA-MB-231 compared to the CCD fibroblast control cell line.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: RSC Adv Año: 2022 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: RSC Adv Año: 2022 Tipo del documento: Article Pais de publicación: Reino Unido