Your browser doesn't support javascript.
loading
Photoinduced inverse vulcanization.
Jia, Jinhong; Liu, Jingjiang; Wang, Zhi-Qiang; Liu, Tao; Yan, Peiyao; Gong, Xue-Qing; Zhao, Chengxi; Chen, Linjiang; Miao, Congcong; Zhao, Wei; Cai, Shanshan Diana; Wang, Xi-Cun; Cooper, Andrew I; Wu, Xiaofeng; Hasell, Tom; Quan, Zheng-Jun.
Afiliación
  • Jia J; College of Chemistry and Chemical Engineering, Gansu International Scientific and Technological Cooperation Base of Water-Retention Chemical Functional Materials, Northwest Normal University, Lanzhou, P. R. China.
  • Liu J; College of Chemistry and Chemical Engineering, Gansu International Scientific and Technological Cooperation Base of Water-Retention Chemical Functional Materials, Northwest Normal University, Lanzhou, P. R. China.
  • Wang ZQ; Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Research Centre, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, P. R. China.
  • Liu T; Leverhulme Research Centre for Functional Materials Design, Materials Innovation Factory, and Department of Chemistry, University of Liverpool, Liverpool, UK.
  • Yan P; Department of Chemistry, University of Liverpool, Liverpool, UK.
  • Gong XQ; Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Research Centre, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, P. R. China. xg
  • Zhao C; Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Research Centre, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, P. R. China.
  • Chen L; Leverhulme Research Centre for Functional Materials Design, Materials Innovation Factory, and Department of Chemistry, University of Liverpool, Liverpool, UK.
  • Miao C; Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Research Centre, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, P. R. China.
  • Zhao W; Leverhulme Research Centre for Functional Materials Design, Materials Innovation Factory, and Department of Chemistry, University of Liverpool, Liverpool, UK.
  • Cai SD; School of Chemistry, University of Birmingham, Edgbaston, Birmingham, UK.
  • Wang XC; College of Chemistry and Chemical Engineering, Gansu International Scientific and Technological Cooperation Base of Water-Retention Chemical Functional Materials, Northwest Normal University, Lanzhou, P. R. China.
  • Cooper AI; Leverhulme Research Centre for Functional Materials Design, Materials Innovation Factory, and Department of Chemistry, University of Liverpool, Liverpool, UK.
  • Wu X; Department of Chemistry, University of Liverpool, Liverpool, UK.
  • Hasell T; College of Chemistry and Chemical Engineering, Gansu International Scientific and Technological Cooperation Base of Water-Retention Chemical Functional Materials, Northwest Normal University, Lanzhou, P. R. China.
  • Quan ZJ; Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Research Centre, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, P. R. China. ai
Nat Chem ; 14(11): 1249-1257, 2022 11.
Article en En | MEDLINE | ID: mdl-36302872
The inverse vulcanization (IV) of elemental sulfur to generate sulfur-rich functional polymers has attracted much recent attention. However, the harsh reaction conditions required, even with metal catalysts, constrains the range of feasible crosslinkers. We report here a photoinduced IV that enables reaction at ambient temperatures, greatly broadening the scope for both substrates and products. These conditions enable volatile and gaseous alkenes and alkynes to be used in IV, leading to sustainable alternatives for environmentally harmful plastics that were hitherto inaccessible. Density functional theory calculations reveal different energy barriers for thermal, catalytic and photoinduced IV processes. This protocol circumvents the long curing times that are common in IV, generates no H2S by-products, and produces high-molecular-weight polymers (up to 460,000 g mol-1) with almost 100% atom economy. This photoinduced IV strategy advances both the fundamental chemistry of IV and its potential industrial application to generate materials from waste feedstocks.
Asunto(s)
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polímeros / Azufre Idioma: En Revista: Nat Chem Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article Pais de publicación: Reino Unido
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polímeros / Azufre Idioma: En Revista: Nat Chem Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article Pais de publicación: Reino Unido