Electric-field-induced coupling of aryl iodides with a nickel(0) complex.

Orchanian, Nicholas M; Guizzo, Sophia; Steigerwald, Michael L; Nuckolls, Colin; Venkataraman, Latha

Orchanian, Nicholas M; Guizzo, Sophia; Steigerwald, Michael L; Nuckolls, Colin; Venkataraman, Latha.

Afiliación

Orchanian NM; Department of Chemistry, Columbia University, New York, New York 10027, USA. mls2064@columbia.edu.
Guizzo S; Department of Applied Physics and Mathematics, Columbia University, New York, New York 10027, USA.
Steigerwald ML; Department of Chemistry, Columbia University, New York, New York 10027, USA. mls2064@columbia.edu.
Nuckolls C; Department of Chemistry, Columbia University, New York, New York 10027, USA. mls2064@columbia.edu.
Venkataraman L; Department of Chemistry, Columbia University, New York, New York 10027, USA. mls2064@columbia.edu.

Chem Commun (Camb) ; 58(90): 12556-12559, 2022 Nov 10.

Article en En | MEDLINE | ID: mdl-36245392

RESUMEN

The formation of carbon-carbon bonds with transition metal reagents serves as a cornerstone of organic synthesis. Here, we show that the reactivity of an otherwise kinetically inert transition metal complex can be induced by an external electric field to affect a coupling reaction. These results highlight the importance of electric field effects in reaction chemistry and offers a new strategy to modulate organometallic reactivity.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido

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