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NiH-catalyzed C(sp3)-Si coupling of alkenes with vinyl chlorosilanes.
Cui, Huanhuan; Niu, Changhao; Xing, Mimi; Zhang, Chun.
Afiliación
  • Cui H; Institute of Molecular Plus, Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University, Weijin Rd. 92, Tianjin 300072, China. chunzhang@tju.edu.cn.
  • Niu C; Institute of Molecular Plus, Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University, Weijin Rd. 92, Tianjin 300072, China. chunzhang@tju.edu.cn.
  • Xing M; Institute of Molecular Plus, Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University, Weijin Rd. 92, Tianjin 300072, China. chunzhang@tju.edu.cn.
  • Zhang C; Institute of Molecular Plus, Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University, Weijin Rd. 92, Tianjin 300072, China. chunzhang@tju.edu.cn.
Chem Commun (Camb) ; 58(85): 11989-11992, 2022 Oct 25.
Article en En | MEDLINE | ID: mdl-36218034
A novel NiH-catalyzed highly regioselective coupling of alkenes with vinyl chlorosilanes, constructing C-Si bonds, is developed. Under mild reaction conditions, a series of benzyl organosilanes with various functional groups could be accessed. Further synthetic studies illustrate that the products of this chemistry could be used as versatile precursors to prepare complicated organosilicon compounds. Moreover, the NiH-catalyzed mechanism of the present transformation was proposed based on control experiments.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido