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Fabrication of a biological metal-organic framework based superhydrophobic textile fabric for efficient oil/water separation.
Mohamed, M E; Abd-El-Nabey, B A.
Afiliación
  • Mohamed ME; Chemistry Department, Faculty of Science, Alexandria University, PO Box 426, Alexandria, 21321, Egypt. elshahatchemist93@gmail.com.
  • Abd-El-Nabey BA; Chemistry Department, Faculty of Science, Alexandria University, PO Box 426, Alexandria, 21321, Egypt.
Sci Rep ; 12(1): 15483, 2022 09 15.
Article en En | MEDLINE | ID: mdl-36109549
In response to the industry's difficulty in properly separating oily wastewater discharge, researchers are investigating enhanced oil/water separation materials. In this work, a cost-effective and environmentally friendly superhydrophobic textile fabric was fabricated for effective oil-water mixture and emulsion separation. A biological metal-organic framework consisting of copper as a core metal and aspartic acid as a linker (Cu-Asp MOF) was used to improve the surface roughness of the pristine textile fabric, and stearic acid was used to lower its surface energy. The thermal gravimetric analysis investigated the prepared Cu-Asp MOF's thermal stability. X-ray spectroscopy and Fourier-transform infrared spectroscopy studied the crystal orientation and chemical composition of the Cu-Asp MOF, Cu-Asp MOF@SA, pristine textile fabric, and superhydrophobic textile fabric, respectively. The surface morphology of the pristine and modified textile fabric was studied by scanning electron microscope. The wettability results showed that the prepared superhydrophobic textile fabric has a water contact angle of 158° ± 1.3 and water sliding angle of 2° ± 0.2°. The prepared superhydrophobic textile fabric showed excellent oil-water mixture and emulsion separation performance, oil absorption capacity, chemical stability, mechanical abrasion resistance, and a high flux rate. These outstanding characteristics of the prepared superhydrophobic textile fabric greatly increase the possibility for practical applications.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Estructuras Metalorgánicas Idioma: En Revista: Sci Rep Año: 2022 Tipo del documento: Article País de afiliación: Egipto Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Estructuras Metalorgánicas Idioma: En Revista: Sci Rep Año: 2022 Tipo del documento: Article País de afiliación: Egipto Pais de publicación: Reino Unido