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Plasmonic colloidal Au nanoparticles in DMSO: a facile synthesis and characterisation.
Dzhagan, Volodymyr; Kapush, Olga; Plokhovska, Svitlana; Buziashvili, Anastasiya; Pirko, Yaroslav; Yeshchenko, Oleg; Yukhymchuk, Volodymyr; Yemets, Alla; Zahn, Dietrich R T.
Afiliación
  • Dzhagan V; V. Lashkaryov Institute of Semiconductors Physics, National Academy of Sciences of Ukraine Kyiv Ukraine dzhagan@isp.kiev.ua.
  • Kapush O; Physics Department, Taras Shevchenko National University of Kyiv 01601 Kyiv Ukraine.
  • Plokhovska S; V. Lashkaryov Institute of Semiconductors Physics, National Academy of Sciences of Ukraine Kyiv Ukraine dzhagan@isp.kiev.ua.
  • Buziashvili A; Department of Cell Biology and Biotechnology, Institute of Food Biotechnology and Genomics, National Academy of Sciences of Ukraine 04123 Kyiv Ukraine.
  • Pirko Y; Department of Cell Biology and Biotechnology, Institute of Food Biotechnology and Genomics, National Academy of Sciences of Ukraine 04123 Kyiv Ukraine.
  • Yeshchenko O; Department of Population Genetics, Institute of Food Biotechnology and Genomics, National Academy of Sciences of Ukraine Osypovskogo str., 2a Kyiv 04123 Ukraine.
  • Yukhymchuk V; Physics Department, Taras Shevchenko National University of Kyiv 01601 Kyiv Ukraine.
  • Yemets A; V. Lashkaryov Institute of Semiconductors Physics, National Academy of Sciences of Ukraine Kyiv Ukraine dzhagan@isp.kiev.ua.
  • Zahn DRT; Department of Cell Biology and Biotechnology, Institute of Food Biotechnology and Genomics, National Academy of Sciences of Ukraine 04123 Kyiv Ukraine.
RSC Adv ; 12(33): 21591-21599, 2022 Jul 21.
Article en En | MEDLINE | ID: mdl-35975078
We report a new pathway for the synthesis of plasmonic gold nanoparticles (Au NPs) in a bio-compatible medium. A modified room temperature approach based on the standard Turkevich synthesis, using sodium citrate as a reducing and stabilizing agent, results in a highly stable colloidal suspension of Au NPs in dimethyl sulfoxide (DMSO). The mean NP size of about 15 nm with a fairly low size distribution is revealed by scanning electron microscopy. The stability test through UV-vis absorption spectroscopy indicates no sign of aggregation for months. The Au NPs are also characterized by X-ray photoelectron, Raman scattering, and FTIR spectroscopies. The stabilisation mechanism of the Au NPs in DMSO is concluded to be similar to that of NPs synthesized in water. The Au NPs obtained in this work are applicable as SERS substrates, as proved by common analytes. In terms of bio-applications, they do not possess such side-effects as pronounced antibacterial activity, based on the tests performed on non-pathogenic Gram-positive or Gram-negative bacteria.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: RSC Adv Año: 2022 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: RSC Adv Año: 2022 Tipo del documento: Article Pais de publicación: Reino Unido