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Chitin Nanocomposite Based on Plasticized Poly(lactic acid)/Poly(3-hydroxybutyrate) (PLA/PHB) Blends as Fully Biodegradable Packaging Materials.
Iglesias-Montes, Magdalena L; Soccio, Michelina; Siracusa, Valentina; Gazzano, Massimo; Lotti, Nadia; Cyras, Viviana P; Manfredi, Liliana B.
Afiliación
  • Iglesias-Montes ML; Instituto de Investigaciones en Ciencia y Tecnología de Materiales, Facultad de Ingeniería, Universidad Nacional de Mar del Plata-Consejo de Investigaciones Científicas y Técnicas, Mar del Plata 7600, Argentina.
  • Soccio M; Department of Civil, Chemical, Environmental and Materials Engineering, University of Bologna, 40131 Bologna, Italy.
  • Siracusa V; Interdepartmental Center for Industrial Research on Advanced Applications in Mechanical Engineering and Materials Technology, CIRI-MAM, University of Bologna, 40126 Bologna, Italy.
  • Gazzano M; Chemical Science Department, University of Catania, Viale A. Doria 6, 95125 Catania, Italy.
  • Lotti N; Institute of Organic Synthesis and Photoreactivity, National Research Council, 40129 Bologna, Italy.
  • Cyras VP; Department of Civil, Chemical, Environmental and Materials Engineering, University of Bologna, 40131 Bologna, Italy.
  • Manfredi LB; Interdepartmental Center for Industrial Research on Advanced Applications in Mechanical Engineering and Materials Technology, CIRI-MAM, University of Bologna, 40126 Bologna, Italy.
Polymers (Basel) ; 14(15)2022 Aug 03.
Article en En | MEDLINE | ID: mdl-35956691
Fully bio-based poly(lactic acid) (PLA) and poly(3-hydroxybutyrate) (PHB) blends plasticized with tributyrin (TB), and their nanocomposite based on chitin nanoparticles (ChNPs) was developed using melt mixing followed by a compression molding process. The combination of PHB and ChNPs had an impact on the crystallinity of the plasticized PLA matrix, thus improving its oxygen and carbon dioxide barrier properties as well as displaying a UV light-blocking effect. The addition of 2 wt% of ChNP induced an improvement on the initial thermal degradation temperature and the overall migration behavior of blends, which had been compromised by the presence of TB. All processed materials were fully disintegrated under composting conditions, suggesting their potential application as fully biodegradable packaging materials.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2022 Tipo del documento: Article País de afiliación: Argentina Pais de publicación: Suiza

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2022 Tipo del documento: Article País de afiliación: Argentina Pais de publicación: Suiza