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Luminescent Lanthanide Probes for Inorganic and Organic Phosphates.
Martinon, Thibaut L M; Pierre, Valérie C.
Afiliación
  • Martinon TLM; Department of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA.
  • Pierre VC; Department of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA.
Chem Asian J ; 17(16): e202200495, 2022 Aug 15.
Article en En | MEDLINE | ID: mdl-35750633
Inorganic and organic phosphates-including orthophosphate, nucleotides, and DNA-are some of the most fundamental anions in cellular biology, regulating numerous processes of both medical and environmental significance. The characteristic long lifetimes of emitting lanthanides, including the brighter europium(III) and terbium(III), make them ideally suited for the development of molecular probes for the detection of phosphates directly in complex aqueous media. Moreover, given their high oxophilicity and the exquisite sensitivity of their quantum yields to their hydration number, those luminescent lanthanides are perfect for the detection of phosphates. Herein we discuss the principles that have guided the recent developments of molecular probes selective for inorganic or organic phosphates and how these lanthanide complexes facilitate the study of numerous biological processes.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Elementos de la Serie de los Lantanoides / Sustancias Luminiscentes Idioma: En Revista: Chem Asian J Año: 2022 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Alemania

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Elementos de la Serie de los Lantanoides / Sustancias Luminiscentes Idioma: En Revista: Chem Asian J Año: 2022 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Alemania