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Hypoxia-Responsive Luminescent CEST MRI Agent for In Vitro and In Vivo Tumor Detection and Imaging.
Karan, Sanu; Cho, Mi Young; Lee, Hyunseung; Park, Hye Sun; Han, Eun Hee; Song, Youngkyu; Lee, Youlee; Kim, Mina; Cho, Jee-Hyun; Sessler, Jonathan L; Hong, Kwan Soo.
Afiliación
  • Karan S; Research Center for Bioconvergence Analysis, Korea Basic Science Institute, Cheongju 28119, Korea.
  • Cho MY; Graduate School of Analytical Science and Technology, Chungnam National University, Daejeon 34134, Korea.
  • Lee H; Research Center for Bioconvergence Analysis, Korea Basic Science Institute, Cheongju 28119, Korea.
  • Park HS; Research Center for Bioconvergence Analysis, Korea Basic Science Institute, Cheongju 28119, Korea.
  • Han EH; Research Center for Bioconvergence Analysis, Korea Basic Science Institute, Cheongju 28119, Korea.
  • Song Y; Research Center for Bioconvergence Analysis, Korea Basic Science Institute, Cheongju 28119, Korea.
  • Lee Y; Research Equipment Operations Division, Korea Basic Science Institute, Cheongju 28119, Korea.
  • Kim M; Research Equipment Operations Division, Korea Basic Science Institute, Cheongju 28119, Korea.
  • Cho JH; Department of Neuroinflammation, UCL Queen Square Institute of Neurology, Faculty of Brain Science, London WC1N 3BG, United Kingdom.
  • Sessler JL; Research Equipment Operations Division, Korea Basic Science Institute, Cheongju 28119, Korea.
  • Hong KS; Department of Chemistry, The University of Texas at Austin, Austin, Texas 78712-1224, United States.
J Med Chem ; 65(10): 7106-7117, 2022 05 26.
Article en En | MEDLINE | ID: mdl-35580357
Hypoxia is a feature of most solid tumors and a key determinant of cancer growth and propagation. Sensing hypoxia effectively could lead to more favorable clinical outcomes. Here, we report a molecular antenna-based bimodal probe designed to exploit the complementary advantages of magnetic resonance (MR)- and optical-based imaging. Specifically, we describe the synthesis and evaluation of a dual-action probe (NO2-Eu) that permits hypoxia-activated chemical exchange saturation transfer (CEST) MR and optical imaging. In CT26 cells, this NO2-Eu probe not only provides an enhanced CEST MRI signal but also turns "on" the optical signal under hypoxic conditions. Time-dependent in vivo CEST imaging in a hypoxic CT26 tumor xenograft mouse model revealed probe-dependent tumor detection by CEST MRI contrast in the tumor area. We thus suggest that dual-action hypoxia probes, like that reported here, could have a role to play in solid tumor diagnosis and monitoring.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Neoplasias / Dióxido de Nitrógeno Tipo de estudio: Diagnostic_studies Límite: Animals / Humans Idioma: En Revista: J Med Chem Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Neoplasias / Dióxido de Nitrógeno Tipo de estudio: Diagnostic_studies Límite: Animals / Humans Idioma: En Revista: J Med Chem Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article Pais de publicación: Estados Unidos