Preparation and facile addition reactions of iminium salts derived from amino ketene silyl acetal and amino silyl enol ether.

Shimizu, Makoto; Hata, Shingo; Kondo, Koichi; Murakami, Kazuhiro; Mizota, Isao; Zhu, Yusong

Shimizu, Makoto; Hata, Shingo; Kondo, Koichi; Murakami, Kazuhiro; Mizota, Isao; Zhu, Yusong.

Afiliación

Shimizu M; School of Energy Science and Engineering, Nanjing Tech University Nanjing 211816 Jiangsu Province China.
Hata S; Department of Chemistry for Materials, Graduate School of Engineering, Mie University Tsu Mie 514-8507 Japan mshimizu@chem.mie-u.ac.jp.
Kondo K; Department of Chemistry for Materials, Graduate School of Engineering, Mie University Tsu Mie 514-8507 Japan mshimizu@chem.mie-u.ac.jp.
Murakami K; Department of Chemistry for Materials, Graduate School of Engineering, Mie University Tsu Mie 514-8507 Japan mshimizu@chem.mie-u.ac.jp.
Mizota I; Department of Chemistry for Materials, Graduate School of Engineering, Mie University Tsu Mie 514-8507 Japan mshimizu@chem.mie-u.ac.jp.
Zhu Y; Department of Chemistry for Materials, Graduate School of Engineering, Mie University Tsu Mie 514-8507 Japan mshimizu@chem.mie-u.ac.jp.

RSC Adv ; 10(46): 27874-27883, 2020 Jul 21.

Article en En | MEDLINE | ID: mdl-35516926

RESUMEN

While iminium salts generated by the oxidation of amino ketene silyl acetals show intriguing reactivities to give useful Î³-oxo-α-amino esters via reactions with silyl enol ethers in good yields, new iminium salts are also prepared by the oxidation of amino silyl enol ethers. They undergo facile addition reaction with various nucleophiles to give α-amino ketone derivatives in good yields.

Texto completo

Añadir a Mi BVS

Imprimir

XML

PubMed Links

Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: RSC Adv Año: 2020 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo

Añadir a Mi BVS

Imprimir

XML

PubMed Links

Buscar en Google