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Synthesis and characterization of pristine and strontium-doped zinc oxide nanoparticles for methyl green photo-degradation application.
Akram, Rizwan; Almohaimeed, Ziyad M; Bashir, Adeela; Ikram, Muhammad; Qadir, Karwan Wasman; Zafar, Qayyum.
Afiliación
  • Akram R; Department of Electrical Engineering, College of Engineering, Qassim University, PO Box 6677-Buraydah, 51452, Saudi Arabia.
  • Almohaimeed ZM; Department of Electrical Engineering, College of Engineering, Qassim University, PO Box 6677-Buraydah, 51452, Saudi Arabia.
  • Bashir A; Department of Physics, University of Management and Technology, 54000-Lahore, Pakistan.
  • Ikram M; Solar Cell Applications Research Lab, Department of Physics, Government College University, 54000-Lahore, Pakistan.
  • Qadir KW; Computation Nanotechnology Research Lab (CNRL), Department of Physics, College of Education, Salahaddin University-Erbil, 44002-Erbil, Kurdistan Region, Iraq.
  • Zafar Q; Department of Physics, University of Management and Technology, 54000-Lahore, Pakistan.
Nanotechnology ; 33(29)2022 May 03.
Article en En | MEDLINE | ID: mdl-35504008
Herein we describe an effective route for the degradation of methyl green (MG) dye under visible light illumination by pristine and strontium (Sr)-doped zinc oxide (ZnO) photocatalysts (synthesized by the simple chemical precipitation method). The x-ray diffraction structural analysis has confirmed that both photocatalysts exhibit the hexagonal wurtzite structure; without any additional phase formation in Sr-doped ZnO, in particular. The optical properties of the synthesized photocatalysts have been investigated using UV-vis absorption spectroscopy in the wavelength range of 250-800 nm. Through Tauc's plot, the slight decrease from 3.3 to 3.2 eV in band gap energy has been elucidated (in the case of Sr-doped ZnO), which has been further confirmed by the quenching in the intensity of Photoluminescence (PL) emission spectrum. This may be due to sub-band level formation between valence and conduction band, caused by the impregnation of Sr2+ions into ZnO host. The morphological study has also been performed using Field Emission Scanning Electron Microscope, which indicates nanoparticles (NPs) based surface texture for both photocatalysts. During the photocatalytic activity study, after 30 min irradiation of visible light, ∼65.7% and ∼84.8% photocatalytic degradation of MG dye has been achieved for pristine and Sr-doped (2 wt%) ZnO photocatalysts, respectively. The rate of photocatalytic reaction (K) has been observed to be âˆ¼0.06399 min-1for Sr-doped (2 wt%), whereas nearly half magnitude âˆ¼0.03403 min-1has been observed for pristine ZnO, respectively. The significantly improved photodegradation activity may be ascribed to the relatively broader optical absorption capability, surface defects and the enhanced charge separation efficiency of the Sr-doped ZnO photocatalyst.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanotechnology Año: 2022 Tipo del documento: Article País de afiliación: Arabia Saudita Pais de publicación: Reino Unido
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanotechnology Año: 2022 Tipo del documento: Article País de afiliación: Arabia Saudita Pais de publicación: Reino Unido