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Goethite-based carbon foam nanocomposites for concurrently immobilizing arsenic and metals in polluted soils.
Janeiro-Tato, I; Baragaño, D; Lopez-Anton, M A; Rodríguez, E; Peláez, A I; García, R; Gallego, J R.
Afiliación
  • Janeiro-Tato I; Instituto de Ciencia y Tecnología Del Carbono, INCAR-CSIC, C/ Francisco Pintado Fe, 26, 33011, Oviedo, Spain; Area of Microbiology, Department of Functional Biology and Environmental Biogeochemistry and Raw Materials Group, University of Oviedo, Oviedo, Spain.
  • Baragaño D; INDUROT and Environmental Biogeochemistry and Raw Materials Group, University of Oviedo, Mieres, Spain.
  • Lopez-Anton MA; Instituto de Ciencia y Tecnología Del Carbono, INCAR-CSIC, C/ Francisco Pintado Fe, 26, 33011, Oviedo, Spain. Electronic address: marian@incar.csic.es.
  • Rodríguez E; Instituto de Ciencia y Tecnología Del Carbono, INCAR-CSIC, C/ Francisco Pintado Fe, 26, 33011, Oviedo, Spain.
  • Peláez AI; Area of Microbiology, Department of Functional Biology and Environmental Biogeochemistry and Raw Materials Group, University of Oviedo, Oviedo, Spain; University Institute of Biotechnology of Asturias (IUBA), University of Oviedo, Oviedo, Spain.
  • García R; Instituto de Ciencia y Tecnología Del Carbono, INCAR-CSIC, C/ Francisco Pintado Fe, 26, 33011, Oviedo, Spain.
  • Gallego JR; INDUROT and Environmental Biogeochemistry and Raw Materials Group, University of Oviedo, Mieres, Spain.
Chemosphere ; 301: 134645, 2022 Aug.
Article en En | MEDLINE | ID: mdl-35439496
Although different amendments have been used for the immobilization of metals and metalloids in contaminated soils, in most of them there are still important challenges that need to be faced in order to achieve an optimal result. In this work, a new material based on a carbon foam impregnated with goethite nanoneedles has been developed with the aim of evaluating its effect on the mobility and availability of As, Cd, Cu, Pb and Zn in an industrial soil. For this purpose, leaching, sequential extraction and phytotoxicity studies have been carried out. The results were compared with the same carbon foam without goethite impregnation. When the soil was treated with goethite-based carbon foam nanocomposite, the mobility of metal(loid)s was markedly reduced, with the exception of Zn, which showed moderate immobilization. The presence of acid groups on the surface of the carbon foam, together with a high surface area, led to a strong immobilization of pollutants. Moreover, the modification of the foams using goethite nanoneedles, imply that the novel nanocomposite obtained is effective to remediate simultaneously metal and metalloid-polluted soils, without any relevant effect on soil toxicity.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Arsénico / Contaminantes del Suelo / Metales Pesados / Nanocompuestos Idioma: En Revista: Chemosphere Año: 2022 Tipo del documento: Article País de afiliación: España Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Arsénico / Contaminantes del Suelo / Metales Pesados / Nanocompuestos Idioma: En Revista: Chemosphere Año: 2022 Tipo del documento: Article País de afiliación: España Pais de publicación: Reino Unido