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Nanostructure Engineering Strategies of Cathode Materials for Room-Temperature Na-S Batteries.
Wang, Ye; Huang, Xiang Long; Liu, Hanwen; Qiu, Weiling; Feng, Chi; Li, Ce; Zhang, Shaohui; Liu, Hua Kun; Dou, Shi Xue; Wang, Zhiming M.
Afiliación
  • Wang Y; Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, P.R. China.
  • Huang XL; Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, P.R. China.
  • Liu H; School of Chemical Engineering, The University of Queensland, St. Lucia, Brisbane, QLD 4072, Australia.
  • Qiu W; Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, P.R. China.
  • Feng C; Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, P.R. China.
  • Li C; Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, P.R. China.
  • Zhang S; Guangdong Provincial Key Laboratory of Micro/Nano Optomechatronic Engineering, College of Mechatronics and Control Engineering, Shenzhen University, Shenzhen 518060, P.R. China.
  • Liu HK; Institute of Superconducting and Electronic Materials, Australian Institute for Innovative Materials, University of Wollongong, Wollongong, NSW 2500, Australia.
  • Dou SX; Institute of Superconducting and Electronic Materials, Australian Institute for Innovative Materials, University of Wollongong, Wollongong, NSW 2500, Australia.
  • Wang ZM; Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, P.R. China.
ACS Nano ; 16(4): 5103-5130, 2022 Apr 26.
Article en En | MEDLINE | ID: mdl-35377602
Room-temperature sodium-sulfur (RT Na-S) batteries are considered to be a competitive electrochemical energy storage system, due to their advantages in abundant natural reserves, inexpensive materials, and superb theoretical energy density. Nevertheless, RT Na-S batteries suffer from a series of critical challenges, especially on the S cathode side, including the insulating nature of S and its discharge products, volumetric fluctuation of S species during the (de)sodiation process, shuttle effect of soluble sodium polysulfides, and sluggish conversion kinetics. Recent studies have shown that nanostructural designs of S-based materials can greatly contribute to alleviating the aforementioned issues via their unique physicochemical properties and architectural features. In this review, we review frontier advancements in nanostructure engineering strategies of S-based cathode materials for RT Na-S batteries in the past decade. Our emphasis is focused on delicate and highly efficient design strategies of material nanostructures as well as interactions of component-structure-property at a nanosize level. We also present our prospects toward further functional engineering and applications of nanostructured S-based materials in RT Na-S batteries and point out some potential developmental directions.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Nano Año: 2022 Tipo del documento: Article Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
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XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Nano Año: 2022 Tipo del documento: Article Pais de publicación: Estados Unidos