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Efficient Electrochemical Nitrate Reduction to Ammonia with Copper-Supported Rhodium Cluster and Single-Atom Catalysts.
Liu, Huimin; Lang, Xiuyao; Zhu, Chao; Timoshenko, Janis; Rüscher, Martina; Bai, Lichen; Guijarro, Néstor; Yin, Haibo; Peng, Yue; Li, Junhua; Liu, Zheng; Wang, Weichao; Cuenya, Beatriz Roldan; Luo, Jingshan.
Afiliación
  • Liu H; Institute of Photoelectronic Thin Film Devices and Technology, Solar Energy Research Center, Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Ministry of Education Engineering Research Center of Thin Film Photoelectronic Technology, Renewable Energy Conversion and Stora
  • Lang X; Institute of Photoelectronic Thin Film Devices and Technology, Solar Energy Research Center, Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Ministry of Education Engineering Research Center of Thin Film Photoelectronic Technology, Renewable Energy Conversion and Stora
  • Zhu C; School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798, Singapore.
  • Timoshenko J; Department of Interface Science, Fritz-Haber-Institut der Max-Planck-Gesellschaft, 14195, Berlin, Germany.
  • Rüscher M; Department of Interface Science, Fritz-Haber-Institut der Max-Planck-Gesellschaft, 14195, Berlin, Germany.
  • Bai L; Department of Interface Science, Fritz-Haber-Institut der Max-Planck-Gesellschaft, 14195, Berlin, Germany.
  • Guijarro N; Institute of Electrochemistry, University of Alicante, 03080, Alicante, Spain.
  • Yin H; State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, China.
  • Peng Y; State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, China.
  • Li J; State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, China.
  • Liu Z; School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798, Singapore.
  • Wang W; Institute of Photoelectronic Thin Film Devices and Technology, Solar Energy Research Center, Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Ministry of Education Engineering Research Center of Thin Film Photoelectronic Technology, Renewable Energy Conversion and Stora
  • Cuenya BR; Department of Interface Science, Fritz-Haber-Institut der Max-Planck-Gesellschaft, 14195, Berlin, Germany.
  • Luo J; Institute of Photoelectronic Thin Film Devices and Technology, Solar Energy Research Center, Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Ministry of Education Engineering Research Center of Thin Film Photoelectronic Technology, Renewable Energy Conversion and Stora
Angew Chem Int Ed Engl ; 61(23): e202202556, 2022 Jun 07.
Article en En | MEDLINE | ID: mdl-35297151
The electrochemical nitrate reduction reaction (NITRR) provides a promising solution for restoring the imbalance in the global nitrogen cycle while enabling a sustainable and decentralized route to source ammonia. Here, we demonstrate a novel electrocatalyst for NITRR consisting of Rh clusters and single-atoms dispersed onto Cu nanowires (NWs), which delivers a partial current density of 162 mA cm-2 for NH3 production and a Faradaic efficiency (FE) of 93 % at -0.2 V vs. RHE. The highest ammonia yield rate reached a record value of 1.27 mmol h-1 cm-2 . Detailed investigations by electron paramagnetic resonance, in situ infrared spectroscopy, differential electrochemical mass spectrometry and density functional theory modeling suggest that the high activity originates from the synergistic catalytic cooperation between Rh and Cu sites, whereby adsorbed hydrogen on Rh site transfers to vicinal *NO intermediate species adsorbed on Cu promoting the hydrogenation and ammonia formation.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2022 Tipo del documento: Article Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2022 Tipo del documento: Article Pais de publicación: Alemania