Ultrasensitive electrode-free and co-catalyst-free detection of nanomoles per hour hydrogen evolution for the discovery of new photocatalysts.
Rev Sci Instrum
; 93(2): 025002, 2022 Feb 01.
Article
en En
| MEDLINE
| ID: mdl-35232165
High throughput theoretical methods are increasingly used to identify promising photocatalytic materials for hydrogen generation from water as a clean source of energy. While most promising water splitting candidates require co-catalyst loading and electrical biasing, computational costs to predict them a priori become large. It is, therefore, important to identify bare, bias-free semiconductor photocatalysts with small initial hydrogen production rates, often in the range of tens of nanomoles per hour, as these can become highly efficient with further co-catalyst loading and biasing. Here, we report a sensitive hydrogen detection system suitable for screening new photocatalysts. The hydrogen evolution rate of the prototypical rutile TiO2 loaded with 0.3 wt. % Pt is detected to be 78.0 ± 0.8 µmol/h/0.04 g, comparable with the rates reported in the literature. In contrast, sensitivity to an ultralow evolution rate of 11.4 ± 0.3 nmol/h/0.04 g is demonstrated for bare polycrystalline TiO2 without electrical bias. Two candidate photocatalysts, ZnFe2O4 (18.1 ± 0.2 nmol/h/0.04 g) and Ca2PbO4 (35.6 ± 0.5 nmol/h/0.04 g) without electrical bias or co-catalyst loading, are demonstrated to be potentially superior to bare TiO2. This work expands the techniques available for sensitive detection of photocatalytic processes toward much faster screening of new candidate photocatalytic materials in their bare state.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Tipo de estudio:
Diagnostic_studies
Idioma:
En
Revista:
Rev Sci Instrum
Año:
2022
Tipo del documento:
Article
País de afiliación:
Estados Unidos
Pais de publicación:
Estados Unidos