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Photoinduced Controlled/Living Polymerizations.
Aydogan, Cansu; Yilmaz, Gorkem; Shegiwal, Ataulla; Haddleton, David M; Yagci, Yusuf.
Afiliación
  • Aydogan C; Department of Chemistry, Faculty of Science and Letters, Istanbul Technical University, 34469, Maslak, Istanbul, Turkey.
  • Yilmaz G; Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.
  • Shegiwal A; Department of Chemistry, Faculty of Science and Letters, Istanbul Technical University, 34469, Maslak, Istanbul, Turkey.
  • Haddleton DM; Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.
  • Yagci Y; Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.
Angew Chem Int Ed Engl ; 61(23): e202117377, 2022 06 07.
Article en En | MEDLINE | ID: mdl-35128771
The application of photochemistry in polymer synthesis is of interest due to the unique possibilities offered compared to thermochemistry, including topological and temporal control, rapid polymerization, sustainable low-energy processes, and environmentally benign features leading to established and emerging applications in adhesives, coatings, adaptive manufacturing, etc. In particular, the utilization of photochemistry in controlled/living polymerizations often offers the capability for precise control over the macromolecular structure and chain length in addition to the associated advantages of photochemistry. Herein, the latest developments in photocontrolled living radical and cationic polymerizations and their combinations for application in polymer syntheses are discussed. This Review summarizes and highlights recent studies in the emerging area of photoinduced controlled/living polymerizations. A discussion of mechanistic details highlights differences as well as parallels between different systems for different polymerization methods and monomer applicability.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polímeros Idioma: En Revista: Angew Chem Int Ed Engl Año: 2022 Tipo del documento: Article País de afiliación: Turquía Pais de publicación: Alemania
Texto completo
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Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polímeros Idioma: En Revista: Angew Chem Int Ed Engl Año: 2022 Tipo del documento: Article País de afiliación: Turquía Pais de publicación: Alemania