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Synthesis and Properties of V-Shaped Xanthene Dyes with Tunable and Predictable Absorption and Emission Wavelengths.
Yamagami, Akari; Kiyotaki, Kotaro; Wakabayashi, Sae; Egami, Naoki; Kawano, Kenichi; Futaki, Shiroh; Imayoshi, Ayumi; Tsubaki, Kazunori.
Afiliación
  • Yamagami A; Graduate School of Life and Environmental Sciences, Kyoto Prefectural University, 1-5 Shimogamo Hangi-cho, Sakyo-ku, Kyoto, Kyoto 606-8522, Japan.
  • Kiyotaki K; Graduate School of Life and Environmental Sciences, Kyoto Prefectural University, 1-5 Shimogamo Hangi-cho, Sakyo-ku, Kyoto, Kyoto 606-8522, Japan.
  • Wakabayashi S; Graduate School of Life and Environmental Sciences, Kyoto Prefectural University, 1-5 Shimogamo Hangi-cho, Sakyo-ku, Kyoto, Kyoto 606-8522, Japan.
  • Egami N; Graduate School of Life and Environmental Sciences, Kyoto Prefectural University, 1-5 Shimogamo Hangi-cho, Sakyo-ku, Kyoto, Kyoto 606-8522, Japan.
  • Kawano K; Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
  • Futaki S; Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
  • Imayoshi A; Graduate School of Life and Environmental Sciences, Kyoto Prefectural University, 1-5 Shimogamo Hangi-cho, Sakyo-ku, Kyoto, Kyoto 606-8522, Japan.
  • Tsubaki K; Graduate School of Life and Environmental Sciences, Kyoto Prefectural University, 1-5 Shimogamo Hangi-cho, Sakyo-ku, Kyoto, Kyoto 606-8522, Japan.
J Org Chem ; 87(5): 2336-2344, 2022 03 04.
Article en En | MEDLINE | ID: mdl-35021008
V-shaped xanthene dyes capable of predicting absorption and emission wavelengths are described. These dyes were synthesized by bridging a xanthene ring and an aryl moiety of fluorescein through ether covalent bonds. These dyes showed longer absorption and emission wavelengths than those of the parent fluorescein. Furthermore, substituents introduced on the aryl moiety mainly affected the lowest unoccupied molecular orbital energy level of the molecule. Therefore, the Hammett substituent constants could be used to predict the absorption and emission wavelengths of the compound.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Xantenos / Colorantes Tipo de estudio: Prognostic_studies / Risk_factors_studies Idioma: En Revista: J Org Chem Año: 2022 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Estados Unidos
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Xantenos / Colorantes Tipo de estudio: Prognostic_studies / Risk_factors_studies Idioma: En Revista: J Org Chem Año: 2022 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Estados Unidos