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Controlling the Anionic Ratio and Gradient in Kesterite Technology.
Andrade-Arvizu, Jacob; Rubio, Robert Fonoll; Izquierdo-Roca, Victor; Becerril-Romero, Ignacio; Sylla, Diouldé; Vidal-Fuentes, Pedro; Li-Kao, Zacharie Jehl; Thomere, Angélica; Giraldo, Sergio; Tiwari, Kunal; Resalati, Shahaboddin; Guc, Maxim; Placidi, Marcel.
Afiliación
  • Andrade-Arvizu J; Solar Energy Materials and Systems (SEMS), Institut de Recerca en Energia de Catalunya (IREC), Jardins de les Dones de Negre 1, Sant Adrià de Besòs, Barcelona 08930, Spain.
  • Rubio RF; Solar Energy Materials and Systems (SEMS), Institut de Recerca en Energia de Catalunya (IREC), Jardins de les Dones de Negre 1, Sant Adrià de Besòs, Barcelona 08930, Spain.
  • Izquierdo-Roca V; Solar Energy Materials and Systems (SEMS), Institut de Recerca en Energia de Catalunya (IREC), Jardins de les Dones de Negre 1, Sant Adrià de Besòs, Barcelona 08930, Spain.
  • Becerril-Romero I; Solar Energy Materials and Systems (SEMS), Institut de Recerca en Energia de Catalunya (IREC), Jardins de les Dones de Negre 1, Sant Adrià de Besòs, Barcelona 08930, Spain.
  • Sylla D; Solar Energy Materials and Systems (SEMS), Institut de Recerca en Energia de Catalunya (IREC), Jardins de les Dones de Negre 1, Sant Adrià de Besòs, Barcelona 08930, Spain.
  • Vidal-Fuentes P; Solar Energy Materials and Systems (SEMS), Institut de Recerca en Energia de Catalunya (IREC), Jardins de les Dones de Negre 1, Sant Adrià de Besòs, Barcelona 08930, Spain.
  • Li-Kao ZJ; Departament d'Enginyeria Electrònica, Universitat Politècnica de Catalunya, C/ Jordi Girona 1, Barcelona 08034, Spain.
  • Thomere A; Solar Energy Materials and Systems (SEMS), Institut de Recerca en Energia de Catalunya (IREC), Jardins de les Dones de Negre 1, Sant Adrià de Besòs, Barcelona 08930, Spain.
  • Giraldo S; Solar Energy Materials and Systems (SEMS), Institut de Recerca en Energia de Catalunya (IREC), Jardins de les Dones de Negre 1, Sant Adrià de Besòs, Barcelona 08930, Spain.
  • Tiwari K; Solar Energy Materials and Systems (SEMS), Institut de Recerca en Energia de Catalunya (IREC), Jardins de les Dones de Negre 1, Sant Adrià de Besòs, Barcelona 08930, Spain.
  • Resalati S; Architectural Engineering Research Group, Oxford Brookes University, Headington Rd, Headington, Oxford OX3 0BP, United Kingdom.
  • Guc M; Solar Energy Materials and Systems (SEMS), Institut de Recerca en Energia de Catalunya (IREC), Jardins de les Dones de Negre 1, Sant Adrià de Besòs, Barcelona 08930, Spain.
  • Placidi M; Solar Energy Materials and Systems (SEMS), Institut de Recerca en Energia de Catalunya (IREC), Jardins de les Dones de Negre 1, Sant Adrià de Besòs, Barcelona 08930, Spain.
ACS Appl Mater Interfaces ; 14(1): 1177-1186, 2022 Jan 12.
Article en En | MEDLINE | ID: mdl-34978180
Accurate anionic control during the formation of chalcogenide solid solutions is fundamental for tuning the physicochemical properties of this class of materials. Compositional grading is the key aspect of band gap engineering and is especially valuable at the device interfaces for an optimum band alignment, for controlling interface defects and recombination and for optimizing the formation of carrier-selective contacts. However, a simple and reliable technique that allows standardizing anionic compositional profiles is currently missing for kesterites and the feasibility of achieving a compositional gradient remains a challenging task. This work aims at addressing these issues by a simple and innovative technique. It basically consists of first preparing a pure sulfide absorber with a specific thickness followed by the synthesis of a pure selenide part of complementary thickness on top of it. Specifically, the technique is applied to the synthesis of Cu2ZnSn(S,Se)4 and Cu2ZnGe(S,Se)4 kesterite absorbers, and a series of characterizations are performed to understand the anionic redistribution within the absorbers. For identical processing conditions, different Se incorporation dynamics is identified for Sn- and Ge-based kesterites, leading to a homogeneous or graded composition in depth. It is first demonstrated that for Sn-based kesterite the anionic composition can be perfectly controlled through the thicknesses ratio of the sulfide and selenide absorber parts. Then, it is demonstrated that for Ge-based kesterite an anionic (Se-S) gradient is obtained and that by adjusting the processing conditions the composition at the back side can be finely tuned. This technique represents an innovative approach that will help to improve the compositional reproducibility and determine a band gap grading strategy pathway for kesterites. Furthermore, due to its simplicity and reliability, the proposed methodology could be extended to other chalcogenide materials.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2022 Tipo del documento: Article País de afiliación: España Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2022 Tipo del documento: Article País de afiliación: España Pais de publicación: Estados Unidos