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Unraveling autoimmune and neurodegenerative diseases by amperometric serological detection of antibodies against aquaporin-4.
Arévalo, Beatriz; Blázquez, Marina; Serafín, Verónica; Montero-Calle, Ana; Calero, Miguel; Valverde, Alejandro; Barderas, Rodrigo; Campuzano, Susana; Yáñez-Sedeño, Paloma; Pingarrón, José M.
Afiliación
  • Arévalo B; Department of Analytical Chemistry, Faculty of Chemistry, Complutense University of Madrid, 28014-Madrid, Spain.
  • Blázquez M; Department of Analytical Chemistry, Faculty of Chemistry, Complutense University of Madrid, 28014-Madrid, Spain.
  • Serafín V; Department of Analytical Chemistry, Faculty of Chemistry, Complutense University of Madrid, 28014-Madrid, Spain.
  • Montero-Calle A; Chronic Disease Programme, UFIEC, Institute of Health Carlos III, Majadahonda, 28220-Madrid, Spain.
  • Calero M; Chronic Disease Programme, UFIEC, Institute of Health Carlos III, Majadahonda, 28220-Madrid, Spain; Alzheimer's Center Reina Sofía Foundation -CIEN Foundation and CIBERNED, Institute of Health Carlos III, Majadahonda, 28220-Madrid, Spain.
  • Valverde A; Department of Analytical Chemistry, Faculty of Chemistry, Complutense University of Madrid, 28014-Madrid, Spain.
  • Barderas R; Chronic Disease Programme, UFIEC, Institute of Health Carlos III, Majadahonda, 28220-Madrid, Spain.
  • Campuzano S; Department of Analytical Chemistry, Faculty of Chemistry, Complutense University of Madrid, 28014-Madrid, Spain. Electronic address: susanacr@quim.ucm.es.
  • Yáñez-Sedeño P; Department of Analytical Chemistry, Faculty of Chemistry, Complutense University of Madrid, 28014-Madrid, Spain. Electronic address: yseo@quim.ucm.es.
  • Pingarrón JM; Department of Analytical Chemistry, Faculty of Chemistry, Complutense University of Madrid, 28014-Madrid, Spain.
Bioelectrochemistry ; 144: 108041, 2022 Apr.
Article en En | MEDLINE | ID: mdl-34929532
This work reports the first electroanalytical bioplatform to date for the determination of antibodies against aquaporin-4 (AQP4-Abs), whose serum level is considered as relevant biomarker for certain autoimmune diseases. The bioplatform relies on the use of magnetic microparticles modified with the biotinylated protein for the capture of specific antibodies. The captured IgGs are enzymatically labelled with a secondary antibody conjugated to the horseradish peroxidase (HRP) enzyme. Amperometric transduction is performed using the H2O2/hydroquinone (HQ) system, which results in a cathodic current variation directly proportional to the concentration of the target antibodies. The evaluation of the analytical and operational characteristics of the developed bioplatform shows that it is competitive in terms of sensitivity with the only biosensor reported to date as well as with the commercially available ELISA kits. The achieved limit of detection value is 8.8 pg mL-1. In addition, compared to ELISA kits, the developed bioplatform is advantageous in terms of cost and point of care operation ability. The bioplatform was applied to the analysis of control serum samples with known AQP4-Abs contents as well as of sera from healthy individuals and patients diagnosed with Systemic Lupus Erythematosus (SLE) and Alzheimer (AD) diseases, providing results in agreement with the ELISA methodology.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Peróxido de Hidrógeno Tipo de estudio: Diagnostic_studies Idioma: En Revista: Bioelectrochemistry Asunto de la revista: BIOQUIMICA Año: 2022 Tipo del documento: Article País de afiliación: España Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Peróxido de Hidrógeno Tipo de estudio: Diagnostic_studies Idioma: En Revista: Bioelectrochemistry Asunto de la revista: BIOQUIMICA Año: 2022 Tipo del documento: Article País de afiliación: España Pais de publicación: Países Bajos