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Photoswitchable Zirconium MOF for Light-Driven Hydrogen Storage.
Butova, Vera V; Burachevskaya, Olga A; Podshibyakin, Vitaly A; Shepelenko, Evgenii N; Tereshchenko, Andrei A; Shapovalova, Svetlana O; Il'in, Oleg I; Bren', Vladimir A; Soldatov, Alexander V.
Afiliación
  • Butova VV; The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russia.
  • Burachevskaya OA; The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russia.
  • Podshibyakin VA; Institute of Physical and Organic Chemistry, Southern Federal University, 344090 Rostov-on-Don, Russia.
  • Shepelenko EN; Federal Research Center the Southern Scientific Center of the Russian Academy of Sciences, 344006 Rostov-on-Don, Russia.
  • Tereshchenko AA; The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russia.
  • Shapovalova SO; The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russia.
  • Il'in OI; Institute of Nanotechnologies, Electronics and Equipment Engineering, Southern Federal University, Shevchenko 2, 347922 Taganrog, Russia.
  • Bren' VA; Institute of Physical and Organic Chemistry, Southern Federal University, 344090 Rostov-on-Don, Russia.
  • Soldatov AV; The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, Russia.
Polymers (Basel) ; 13(22)2021 Nov 22.
Article en En | MEDLINE | ID: mdl-34833350
Here, we report a new photosensitive metal-organic framework (MOF) that was constructed via the modification of UiO-66-NH2 with diarylethene molecules (DAE, 4-(5-Methoxy-1,2-dimethyl-1H-indol-3-yl)-3-(2,5-dimethylthiophen-3-yl)-4-furan-2,5-dione). The material that was obtained was a highly crystalline porous compound. The photoresponse of the modified MOF was observed via UV-Vis and IR spectroscopy. Most of the DAE molecules inside of the UiO-66-pores had an open conformation after synthesis. However, the equilibrium was able to be shifted further toward an open conformation using visible light irradiation with a wavelength of 520 nm. Conversely, UV-light with a wavelength of 450 nm initiated the transformation of the photoresponsive moieties inside of the pores to a closed modification. We have shown that this transformation could be used to stimulate hydrogen adsorption-desorption processes. Specifically, visible light irradiation increased the H2 capacity of modified MOF, while UV-light decreased it. A similar hybrid material with DAE moieties in the UiO-66 scaffold was applied for hydrogen storage for the first time. Additionally, the obtained results are promising for smart H2 storage that is able to be managed via light stimuli.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2021 Tipo del documento: Article País de afiliación: Rusia Pais de publicación: Suiza
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Polymers (Basel) Año: 2021 Tipo del documento: Article País de afiliación: Rusia Pais de publicación: Suiza