Your browser doesn't support javascript.
loading
Vectorial Catalysis in Surface-Anchored Nanometer-Sized Metal-Organic Frameworks-Based Microfluidic Devices.
Semrau, Anna Lisa; Stanley, Philip M; Huber, Dominik; Schuster, Michael; Albada, Bauke; Zuilhof, Han; Cokoja, Mirza; Fischer, Roland A.
Afiliación
  • Semrau AL; Department of Chemistry, Inorganic and Metal-Organic Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85787, Garching, Germany.
  • Stanley PM; Department of Chemistry, Inorganic and Metal-Organic Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85787, Garching, Germany.
  • Huber D; Department of Chemistry, Analytical Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85787, Garching, Germany.
  • Schuster M; Department of Chemistry, Analytical Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85787, Garching, Germany.
  • Albada B; Laboratory of Organic Chemistry, Wageningen University and Research, Stippeneng 4, 6708WE, Wageningen, The Netherlands.
  • Zuilhof H; Laboratory of Organic Chemistry, Wageningen University and Research, Stippeneng 4, 6708WE, Wageningen, The Netherlands.
  • Cokoja M; School of Pharmaceutical Sciences and Technology, Tianjin University, 300072, Tianjin, China.
  • Fischer RA; Department of Chemical and Materials Engineering, Faculty of Engineering, King Abdulaziz University, 21589, Jeddah, Saudi Arabia.
Angew Chem Int Ed Engl ; 61(8): e202115100, 2022 02 14.
Article en En | MEDLINE | ID: mdl-34825766
Vectorial catalysis-controlling multi-step reactions in a programmed sequence and by defined spatial localization in a microscale device-is an enticing goal in bio-inspired catalysis research. However, translating concepts from natural cascade biocatalysis into artificial hierarchical chemical systems remains a challenge. Herein, we demonstrate integration of two different surface-anchored nanometer-sized metal-organic frameworks (MOFs) in a microfluidic device for modelling vectorial catalysis. Catalyst immobilization at defined sections along the microchannel and a two-step cascade reaction was conducted with full conversion after 30 seconds and high turnover frequencies (TOF≈105  h-1 ).
Palabras clave
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2022 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Alemania
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Año: 2022 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Alemania