Origin of the different reactivity of the high-valent coinage-metal complexes [RCuiii Me3 ]- and [RAgiii Me3 ]- (R=allyl).

Auth, Thomas; Stein, Christopher J; O'Hair, Richard A J; Koszinowski, Konrad

Origin of the different reactivity of the high-valent coinage-metal complexes [RCuⁱⁱⁱ Me₃ ]^- and [RAgⁱⁱⁱ Me₃ ]^- (R=allyl).

Auth, Thomas; Stein, Christopher J; O'Hair, Richard A J; Koszinowski, Konrad.

Afiliación

Auth T; Institut für Organische und Biomolekulare Chemie, Universität Göttingen, Tammannstr. 2, 37077, Göttingen, Germany.
Stein CJ; Theoretical Physics and Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, 47048, Duisburg, Germany.
O'Hair RAJ; School of Chemistry and Bio21 Molecular Science and Biotechnology Institute, University of Melbourne, 30 Flemington Rd, Parkville, Victoria, 3010, Australia.
Koszinowski K; Institut für Organische und Biomolekulare Chemie, Universität Göttingen, Tammannstr. 2, 37077, Göttingen, Germany.

Chemistry ; 28(7): e202103130, 2022 Feb 01.

Article en En | MEDLINE | ID: mdl-34773654

Palabras clave

Ab initio calculations; C−C coupling; coinage-metal complexes; kinetics; mass spectrometry

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: Alemania Pais de publicación: Alemania

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