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Synthesis and photodynamic efficacy of water-soluble protoporphyrin IX homologue with mPEG550.
Basoglu, Harun; Degirmencioglu, Ismail; Eyupoglu, Figen Celep.
Afiliación
  • Basoglu H; Faculty of Medicine, Department of Biophysics, Karadeniz Technical University, Trabzon, Turkey. Electronic address: hbasoglu@ktu.edu.tr.
  • Degirmencioglu I; Faculty of Science, Department of Chemistry, Karadeniz Technical University, Trabzon, Turkey.
  • Eyupoglu FC; Faculty of Medicine, Department of Medical Biology, Karadeniz Technical University, Trabzon, Turkey.
Photodiagnosis Photodyn Ther ; 36: 102615, 2021 Dec.
Article en En | MEDLINE | ID: mdl-34740838
Protoporphyrin IX (PpIX), which is an efficient photosensitive agent, cannot be used directly in photodynamic therapy due to its aggregation in physiological environment. If PpIX is made water-soluble without losing its photosensitive properties, it can be used in many medical fields, including cancer treatment. Here we report synthesis of PpIX homologue with mPEG550 (Porfipeg) and its photodynamic effects on both in-vitro and in-vivo environment. Porfipeg is synthesized to give PpIX the ability to dissolve in water. Spectrometric (FT-IR, NMR, MS, UV-vis and Fluorescence) measurements were performed. Porfipeg can penetrate into the cells and indicates no cytotoxicity in the dark whereas cell viability significantly reduced with light irradiation. The cells can be visualized by fluorescence microscope. In-vivo experiment revealed that intravenous injection of Porfipeg is more efficient than intraperitoneal injection for the acute photodynamic effects within 30 min. Moreover it is excreted by the kidneys. In conclusion, Porfipeg has remarkable potentials to be used in both fluorescence guidance in surgeries and photodynamic therapy for cancer treatment.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fotoquimioterapia Tipo de estudio: Guideline Idioma: En Revista: Photodiagnosis Photodyn Ther Asunto de la revista: DIAGNOSTICO POR IMAGEM / TERAPEUTICA Año: 2021 Tipo del documento: Article Pais de publicación: Países Bajos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Fotoquimioterapia Tipo de estudio: Guideline Idioma: En Revista: Photodiagnosis Photodyn Ther Asunto de la revista: DIAGNOSTICO POR IMAGEM / TERAPEUTICA Año: 2021 Tipo del documento: Article Pais de publicación: Países Bajos