Your browser doesn't support javascript.
loading
B,N-Embedded Double Hetero[7]helicenes with Strong Chiroptical Responses in the Visible Light Region.
Li, Ji-Kun; Chen, Xing-Yu; Guo, Yun-Long; Wang, Xin-Chang; Sue, Andrew C-H; Cao, Xiao-Yu; Wang, Xiao-Ye.
Afiliación
  • Li JK; State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.
  • Chen XY; State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.
  • Guo YL; College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
  • Wang XC; College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
  • Sue AC; College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
  • Cao XY; College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
  • Wang XY; State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.
J Am Chem Soc ; 143(43): 17958-17963, 2021 Nov 03.
Article en En | MEDLINE | ID: mdl-34665638
The development of helicene molecules with significant chiroptical responses covering a broad range of the visible spectrum is highly desirable for chiral optoelectronic applications; however, their absorption dissymmetry factors (gabs) have been mostly lower than 0.01. In this work, we report unprecedented B,N-embedded double hetero[7]helicenes with nonbonded B and N atoms, which exhibit excellent chiroptical properties, such as strong chiroptical activities from 300 to 700 nm, record high gabs up to 0.033 in the visible spectral range, and tunable circularly polarized luminescence (CPL) from red to near-infrared regions (600-800 nm) with high photoluminescence quantum yields (PLQYs) up to 100%. As revealed by theoretical analyses, the high gabs values are related to the separate molecular orbital distributions owing to the incorporation of nonbonded B and N atoms. The new type of B,N-embedded double heterohelicenes opens up an appealing avenue to the future exploitation of high-performance chiroptical materials.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2021 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2021 Tipo del documento: Article País de afiliación: China Pais de publicación: Estados Unidos