A new potassium dual-ion hybrid supercapacitor based on battery-type Ni(OH)2 nanotube arrays and pseudocapacitor-type V2O5-anchored carbon nanotubes electrodes.
J Colloid Interface Sci
; 607(Pt 1): 462-469, 2022 Feb.
Article
en En
| MEDLINE
| ID: mdl-34509728
Hybrid supercapacitors (HSCs) with the characteristics of high energy density, long cycle life and without altering their power density need to be developed urgently. Herein, a novel dual-ion hybrid supercapacitors (DHSCs) with Ni(OH)2 nanotube arrays (NTAs) as positive electrode and V2O5 directly grown on freestanding carbon nanotubes (CNTs) as negative electrode is assembled. In charging mechanism of DHSCs, K+ are inserted into the V2O5 negative while OH- react with Ni(OH)2 positive; during discharge, the K+ and OH- are released from V2O5 negative and Ni(OH)2 positive, respectively, and return back to the electrolyte, which is quite different from traditional metal ion or alkaline supercapacitors. Because of the merits combining dual-ion mechanism and HSCs, the DHSC displays excellent capacity retention of â¼ 81.4% after 10,000 cycles, high energy density of â¼ 25.4 µWh cm-2 and high power density of â¼ 4.66 mW cm-2, indicating the potential applications in the further on flexible wearable electronics.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
J Colloid Interface Sci
Año:
2022
Tipo del documento:
Article
País de afiliación:
China
Pais de publicación:
Estados Unidos