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Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions.
Milosevic, Dragana; Levic, Steva; Lazarevic, Slavica; Velickovic, Zlate; Marinkovic, Aleksandar; Petrovic, Rada; Petrovic, Predrag.
Afiliación
  • Milosevic D; University of Belgrade - Institute of Chemistry, Technology and Metallurgy - National Institute of the Republic of Serbia, Department of Ecology and Technoeconomics, Njegoseva 12, 11001, Belgrade, Serbia. Electronic address: dragana.milosevic@ihtm.bg.ac.rs.
  • Levic S; University of Belgrade, Faculty of Agriculture, Nemanjina 6, 11080, Zemun, Serbia.
  • Lazarevic S; University of Belgrade, Faculty of Technology and Metallurgy, Karnegijeva 4, 11060, Belgrade, Serbia.
  • Velickovic Z; University of Defense, Military Academy, Veljka Lukica Kurjaka 33, 11000, Belgrade, Serbia.
  • Marinkovic A; University of Belgrade, Faculty of Technology and Metallurgy, Karnegijeva 4, 11060, Belgrade, Serbia.
  • Petrovic R; University of Belgrade, Faculty of Technology and Metallurgy, Karnegijeva 4, 11060, Belgrade, Serbia.
  • Petrovic P; Innovation Center, Faculty of Technology and Metallurgy, Karnegijeva 4, 11120, Belgrade, Serbia.
J Environ Manage ; 297: 113358, 2021 Nov 01.
Article en En | MEDLINE | ID: mdl-34311248
The alkali treated subglebal tissue of the mosaic puffball (Handkea utriformis) (Sa) and Sa modified with hydroxyapatite (Sa-HAp), obtained by successive ionic layer adsorption and reaction (SILAR) method, were used for the removal of Pb2+, Cd2+ and Ni2+ from aqueous solution. The materials were characterized by FT-IR, Raman, SEM and EDS analysis and by determination of pHPZC. The adsorption performances of Sa and Sa-HAp were assessed in batch experiments at different pH, contact times, temperatures and mass of the adsorbent. Different models of adsorption isotherms were used, and the best fit was obtained with the Langmuir model. Maximum adsorption capacities of Sa towards Pb2+, Cd2+ and Ni2+ were 44.82, 15.54 and 17.21 mg g-1, while for Sa-HAp were 79.55, 52.59 and 45.01 mg g-1, respectively. Kinetic data were well fitted by a pseudo second-order model, while thermodynamic studies disclose spontaneous and endothermic adsorption process. The Sa-Hap was successfully regenerated with 1 M NaCl and after the fifth desorption cycle and 10 h achieved 82.9, 69.7 and 60.4 %, while for 0.5 M NaCl + 0.5 M NaOH and 1 h was 78.3, 64.1, 57.5 % of desorbed Pb2+, Cd2+ and Ni2+, respectively. The competitive study and results from a column system confirmed good applicability of Sa-HAp adsorbent.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Contaminantes Químicos del Agua / Metales Pesados / Agaricales Idioma: En Revista: J Environ Manage Año: 2021 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Contaminantes Químicos del Agua / Metales Pesados / Agaricales Idioma: En Revista: J Environ Manage Año: 2021 Tipo del documento: Article Pais de publicación: Reino Unido